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449628

Sigma-Aldrich

Aluminum fluoride

anhydrous, powder, 99.8% trace metals basis

Synonym(s):

Aluminum trifluoride, Trifluoroaluminum

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About This Item

Linear Formula:
AlF3
CAS Number:
Molecular Weight:
83.98
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
grade:
anhydrous
form:
powder
Pricing and availability is not currently available.

grade

anhydrous

Quality Level

Assay

99.8% trace metals basis

form

powder

impurities

≤1,000.0 ppm Trace Metal Analysis

mp

1290 °C (lit.)

density

3.1 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

F[Al](F)F

InChI

1S/Al.3FH/h;3*1H/q+3;;;/p-3

InChI key

KLZUFWVZNOTSEM-UHFFFAOYSA-K

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Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Optics Communications, 132, 73-73 (1996)
Lecoq, A.; et al.
Non-Cryst. Solids, 41, 209-209 (1980)
Applied Physics Letters, 69, 2012-2012 (1996)
Xiaoyan Jin et al.
Environmental science & technology, 45(1), 288-293 (2010-12-08)
Density functional theory (DFT) calculation is carried out to investigate the structures, (19)F and (27)Al NMR chemical shifts of aqueous Al-F complexes and their water-exchange reactions. The following investigations are performed in this paper: (1) the microscopic properties of typical
Dinesh Shetty et al.
Chemical communications (Cambridge, England), 47(34), 9732-9734 (2011-07-22)
A single crystal structure of an aluminium-fluoride complex of a model compound (NODA-benzyl) was studied to understand the co-ordination chemistry. Series of ligands with an extra carboxylic acid linker for biomolecule conjugation were studied for improved (18)F-labeling applications.

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. How to prepare 0.5M AlF3?

    1 answer
    1. This product is not tested for solubility but is reportedly slightly soluble in water. The SDS suggests 5.3 mg/L. This is much lower than the desired 0.5 M. Other sources show a higher solubility in water as the PubChem information demonstrates. It would appear that 0.5 M may be far beyond the limitations of solubility for this product.

      https://pubchem.ncbi.nlm.nih.gov/compound/Aluminum-fluoride#section=Solubility
      0.559 g/100 mL or 5.59 g/L = about 66 mM.

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