Skip to Content
Merck

43162

Sigma-Aldrich

2-(Diphenylphosphino)ethylamine

≥95.0% (GC)

Synonym(s):

(2-Aminoethyl)diphenylphosphine, 1-Amino-2-(diphenylphosphino)ethane

Sign Into View Organizational & Contract Pricing

Select a Size

1 MG
MXP 1,480.00

MXP 1,480.00


Availability

Available to ship onJanuary 02, 2025Details


Request a Bulk Order

Select a Size

Change View
1 MG
MXP 1,480.00

About This Item

Empirical Formula (Hill Notation):
C14H16NP
CAS Number:
Molecular Weight:
229.26
Beilstein:
644931
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

MXP 1,480.00


Availability

Available to ship onJanuary 02, 2025Details


Request a Bulk Order

Quality Level

Assay

≥95.0% (GC)

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

functional group

phosphine

SMILES string

NCCP(c1ccccc1)c2ccccc2

InChI

1S/C14H16NP/c15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-10H,11-12,15H2

InChI key

RXEPBCWNHKZECN-UHFFFAOYSA-N

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
748277567728287954
assay

≥95.0% (GC)

assay

97%

assay

98%

assay

98%

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

form

liquid

form

liquid

form

-

form

solid

General description

2-(Diphenylphosphino)ethylamine is a phosphine ligand that has a bidentate structure with the phosphorus atom donating two lone pair electrons to coordinate with metal atoms. It is used as a reactant to synthesize active catalyst for the selective hydrogenation of amides. In addition, it is also used as a precursor to synthesize other phosphine ligands.[1] [2]

Application

2-(Diphenylphosphino)ethylamine can be used as a bidentate ligand in the nickel catalyst system for the reductive [2+2] cycloaddition reaction to synthesize cyclobutenes from alkynes.[3]

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Rhodium-P, O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions
Dalton Transactions, 39(8), 1929-1931 (2010)
A highly active catalyst for the hydrogenation of amides to alcohols and amines
Angewandte Chemie (International Edition in English), 50(44), 10377-10380 (2011)
Nickel-catalyzed reductive [2+ 2] cycloaddition of alkynes
Canellas S, et al.
Journal of the American Chemical Society, 140(50), 17349-17355 (2018)
Youngwon Kim et al.
Journal of inorganic biochemistry, 205, 111015-111015 (2020-02-08)
A pyrrolyl-iminophosphine (PNNH) which would act as a potential terdentate ligand has been prepared by Schiff base reaction. Complexes [M(PNN)X] (M = Ni; X = Cl (1), Pd; X = Cl (2), Br (3), I (4), M = Pt; X = Cl (5)) were prepared. The title complexes were characterized

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service