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204757

Sigma-Aldrich

Titanium(IV) oxide, rutile

≥99.98% trace metals basis

Synonym(s):

Titanium dioxide

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About This Item

Linear Formula:
TiO2
CAS Number:
1317-80-2
Molecular Weight:
79.87
EC Number:
215-282-2
MDL number:
MFCD00011269
UNSPSC Code:
12352303
PubChem Substance ID:
24852292
NACRES:
NA.23

Quality Level

100

Assay

≥99.98% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: titanium

density

4.17 g/mL at 25 °C (lit.)

SMILES string

O=[Ti]=O

InChI

1S/2O.Ti

InChI key

GWEVSGVZZGPLCZ-UHFFFAOYSA-N

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General description

Titanium(IV) oxide is a semiconductor with asmaller band gap of 3.0 eV. Among the polymorphs of TiO2, rutile isthe most stable phase in wide temperature and pressure ranges. It is widelyused as a photocatalyst in electrochemical water-splitting reactions and alsofinds application in the field of photovoltaics, sensors, and environmentalremediation.

Application

Titanium(IV) oxide can be used as a photocatalyst for an overall water-splitting reaction. It can also be used as an efficient catalyst for phenol degradation under visible light.

Features and Benefits

  • Chemical stability
  • Non-toxicity
  • Excellent stability against photocorrosion
  • Ease of further functionalization
Possesses improved photocatalytic activity.

Other Notes

Contains ~5% anatase

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000332076
0000332076
MKCV6394
MKCK1522
MKCH7573

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Suxin Gui et al.
Journal of agricultural and food chemistry, 61(37), 8959-8968 (2013-08-24)
TiO₂ nanoparticles (NPs) are used in the food industry but have potential toxic effects in humans and animals. TiO₂ NPs impair renal function and cause oxidative stress and renal inflammation in mice, associated with inhibition of nuclear factor erythroid-2-related factor
D Minetto et al.
Environment international, 66, 18-27 (2014-02-11)
The innovative properties of nanomaterials make them suitable for various applications in many fields. In particular, TiO2 nanoparticles (nTiO2) are widely used in paints, in cosmetics and in sunscreens that are products accessible to the mass market. Despite the great
Roberta Tassinari et al.
Nanotoxicology, 8(6), 654-662 (2013-07-10)
The study explored possible reproductive and endocrine effects of short-term (5 days) oral exposure to anatase TiO2 nanoparticles (0, 1, 2 mg/kg body weight per day) in rat. Nanoparticles were characterised by scanning electron microscopy (SEM) and transmission electron microscopy
Nabila Haddou et al.
Chemosphere, 107, 304-310 (2014-01-28)
The Gliding Arc Discharge (GAD) is an efficient non-thermal plasma technique able to degrade organic compounds dispersed in water at atmospheric pressure. The degradation of the organometallic lead acetate (PbAc) in aqueous solution was performed by two distinct plasmageneous processes:
Elisa Moschini et al.
Toxicology letters, 222(2), 102-116 (2013-08-03)
Metal oxide NPs are abundantly produced in nanotech industries and are emitted in several combustion processes, suggesting the need to characterize their toxic impact on the human respiratory system. The acute toxicity and the morphological changes induced by copper oxide
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