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Key Documents

197637

Sigma-Aldrich

Imidazole sodium derivative

technical grade

Synonym(s):

Imidazolylsodium, Sodium imidazolide

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About This Item

Empirical Formula (Hill Notation):
C3H3N2Na
CAS Number:
Molecular Weight:
90.06
Beilstein:
3569312
EC Number:
MDL number:
UNSPSC Code:
12352005
eCl@ss:
39161001
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

mp

284 °C (dec.) (lit.)

SMILES string

[Na]n1ccnc1

InChI

1S/C3H3N2.Na/c1-2-5-3-4-1;/h1-3H;/q-1;+1

InChI key

ITAWMPSVROAMOE-UHFFFAOYSA-N

Application

Imidazole sodium derivative (Imidazolylsodium) was used in the synthesis of arylazidoamorphigenin.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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F G Earley et al.
The Biochemical journal, 224(2), 525-534 (1984-12-01)
A photoaffinity-labelling analogue of the respiratory inhibitor rotenone was synthesized from the naturally occurring rotenoid amorphigenin. The analogue inhibits NADH-ubiquinone oxidoreductase activity at concentrations comparable with those of rotenone. Photolysis of the radiolabelled analogue bound to isolated NADH-ubiquinone oxidoreductase resulted
Yun Dai et al.
Electrophoresis, 34(6), 833-840 (2013-01-22)
The first member of the single-isomer, dicationic cyclodextrin (CD) family, 6(A)-ammonium-6(C)-butylimidazolium-β-cyclodextrin chlorides (AMBIMCD), has been synthesized, analytically characterized, and used to separate a variety of acidic enantiomers and amino acids by CE. Starting from mono-6(A)-azido-β-cyclodextrin, the cationic imidazolium and ammonium
Lizhen Qiao et al.
Journal of chromatography. A, 1286, 137-145 (2013-03-16)
Hydrophilic interaction liquid chromatography (HILIC) has been widely used for separating polar compounds as a complement mode to reversed-phase liquid chromatography. The development of new stationary phases for HILIC is significant to improve the coverage of various polar and hydrophilic
Kushal Sengupta et al.
Inorganic chemistry, 52(4), 2000-2014 (2013-01-30)
Electrodes bearing thiolate and imidazole coordinated iron porphyrin catalysts are constructed and characterized using resonance Raman spectroscopy, absorption spectroscopy, and electrochemistry. The cyclic voltammetry data and their pH dependences are used to establish the nature of the exchangeable trans ligands
Yin Gao et al.
Bioorganic & medicinal chemistry, 21(5), 1305-1311 (2013-02-05)
Galactosyltransferases (GalTs) extend the glycan chains of mammalian glycoproteins by adding Gal to terminal GlcNAc residues, and thus build the scaffolds for biologically important glycan structures. We have shown that positively charged bivalent imidazolium salts in which the two imidazolium

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