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About This Item
Linear Formula:
CCl3C(=NH)OCH3
CAS Number:
Molecular Weight:
176.43
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
form
liquid
refractive index
n20/D 1.478 (lit.)
bp
148-149 °C (lit.)
density
1.425 g/mL at 25 °C (lit.)
functional group
chloro
storage temp.
2-8°C
SMILES string
COC(=N)C(Cl)(Cl)Cl
InChI
1S/C3H4Cl3NO/c1-8-2(7)3(4,5)6/h7H,1H3
InChI key
OGBINJLTBZWRRB-UHFFFAOYSA-N
Related Categories
Application
Methyl 2,2,2-trichloroacetimidate was used as starting material during the synthesis of novel bibenzimidazole oligomers and polymers. It was employed as reagent during the synthesis of 2,2′-bisbenzimidazole-5,5′-dicarboxylic acid.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
165.2 °F - closed cup
Flash Point(C)
74 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Gulledge AL, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 50(2), 306-313 (2012)
Jun Yin et al.
The Journal of organic chemistry, 70(23), 9436-9446 (2005-11-05)
[Structure: see text]. A simple and mild condensation route for the synthesis of novel bibenzimidazole oligomers and polymers is reported here using methyl 2,2,2-trichloroacetimidate as a key starting material. The dimer, trimer, tetramer, and polymers of bibenzimidazole were synthesized as
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