119792

Podocarpic acid

98%

• Synonym(s): (+)-Podocarpic acid, (1S)-1,2,3,4,4a,9,10,10a-Octahydro-6-hydroxy-1,4a-dimethyl-1-phenanthrenecarboxylic acid, (1S,4aS,10aR)-1,2,3,4,4a,9,10,10a-Octahydro-6-hydroxy-1,4a-dimethyl-1-phenanthrenecarboxylic acid, Podocarpic acid (resin acid)
• Empirical Formula (Hill Notation): C₁₇H₂₂O₃
• CAS Number: 5947-49-9
• Molecular Weight: 274.35
• EC Number: 227-706-3
• MDL number: MFCD00074825
• UNSPSC Code: 12352002
• PubChem Substance ID: 24847299
• NACRES: NA.22

Properties

• Assay: 98%
• form: solid
• optical activity: [α]20/D +133°, c = 4 in ethanol
• mp: 193-196 °C (lit.)
• functional group: carboxylic acid
• SMILES string: [H][C@@]12CCc3ccc(O)cc3[C@@]1(C)CCC[C@]2(C)C(O)=O
• InChI: 1S/C17H22O3/c1-16-8-3-9-17(2,15(19)20)14(16)7-5-11-4-6-12(18)10-13(11)16/h4,6,10,14,18H,3,5,7-9H2,1-2H3,(H,19,20)/t14-,16-,17+/m1/s1
• InChI key: VJILEYKNALCDDV-OIISXLGYSA-N
• Gene Information: human ... TNF(7124)

Description

Application

• (+)-Podocarpic acid as chiral template in the synthesis of aphidicolane, stemodane and stemarane diterpenoids: This article reviews the use of (+)-podocarpic acid in the synthesis of various diterpenoids, showcasing its utility in complex organic syntheses (La Bella et al., 2016).

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves