793841
2,2-Difluoroacetophenone
Synonym(s):
α,α-Difluoroacetophenone, 2,2-Difluoro-1-phenylethanone, Difluoromethyl phenyl ketone
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About This Item
Empirical Formula (Hill Notation):
C8H6F2O
CAS Number:
Molecular Weight:
156.13
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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form
liquid
density
1.180±0.06 g/mL
functional group
fluoro
ketone
phenyl
SMILES string
FC(F)C(C1=CC=CC=C1)=O
InChI
1S/C8H6F2O/c9-8(10)7(11)6-4-2-1-3-5-6/h1-5,8H
InChI key
OLYKCPDTXVZOQF-UHFFFAOYSA-N
Application
Product was reported by Hartwig and coworkers in the one-pot synthesis of difluoromethylated arenes from aryl chlorides and bromides.
Pd-Catalyzed a-Arylation of a;a-Difluoroketones with Aryl Bromides and Chlorides. A Route to Difluoromethylarenes
Pd-Catalyzed a-Arylation of a;a-Difluoroketones with Aryl Bromides and Chlorides. A Route to Difluoromethylarenes
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Description
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
158.0 °F
Flash Point(C)
70 °C
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Professor Hartwig's research focuses on the discovery and understanding of new reactions catalyzed by transition metal complexes.
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