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412910

Sigma-Aldrich

Methyltrioxorhenium(VII)

Methyltrioxorhenium(VII)

Re 71.0-76.0 %

Synonym(s):

MTO, Methylrhenium(VII) trioxide

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About This Item

Linear Formula:
CH3ReO3
CAS Number:
70197-13-6
Molecular Weight:
249.24
Beilstein:
3927932
MDL number:
MFCD00192332
UNSPSC Code:
12161600
PubChem Substance ID:
24865831
NACRES:
NA.22
Pricing and availability is not currently available.

form

solid

Quality Level

100

composition

Re, 71.0-76.0%

reaction suitability

core: rhenium
reagent type: catalyst

mp

111 °C (lit.)

SMILES string

C[Re](=O)(=O)=O

InChI

1S/CH3.3O.Re/h1H3;;;;

InChI key

PQTLALPZRPFYIT-UHFFFAOYSA-N

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Application

Potent catalytic oxidant[1][2] for converting alkenes to epoxides in a variety of solvents[3] and 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone (Vitamin K3).[4][5]
Catalytic oxidant used with urea hydrogen peroxide in an efficient conversion of imines to nitrones.[6]
An effective antioxidant under various conditions.[7][8][9]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM5661
BCCG1736
BCCJ3711
BCCC5797
BCBZ6795

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Aldrichimica Acta, 28, 55-55 (1995)
Applied Homogeneous Catalysis with Organometallic Compounds, 3, 1304-1304 (2002)
Christina Janko et al.
International journal of molecular sciences, 14(4), 7341-7355 (2013-04-04)
Magnetic drug targeting (MDT) improves the integrity of healthy tissues and cells during treatment with cytotoxic drugs. An anticancer drug is bound to superparamagnetic iron oxide nanoparticles (SPION), injected into the vascular supply of the tumor and directed into the
R Pasquariello et al.
Theriogenology, 145, 77-85 (2020-02-01)
Developmental competence determines the oocyte capacity to support initial embryo growth, but the molecular mechanisms underlying this phenomenon are still ill-defined. Changes in microRNA (miRNA) expression pattern have been described during follicular growth in several species. Therefore, aim of this
Anna Fitzpatrick et al.
Journal of sports sciences, 35(22), 2204-2210 (2016-12-03)
The Lawn Tennis Association's mini tennis (MT) is a modified version of tennis consisting of progressive stages; however, there have been few attempts to evaluate how MT might shape performance behaviours. Here, we examine effects of playing MT on the
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Questions

  1. Is the solubility of Methyltrioxorhenium(VII) in water and in acetonitrile (or in any other organic solvent at least) known?

    1 answer

    1. Unfortunately, solubility assays have been performed internally on Product 412910. However, various online sources indicate that this chemical is soluble in water although no specific concentration is provided.

      Please see the article below for more information:
      https://onlinelibrary.wiley.com/doi/10.1002/047084289X.rn00017.pub3

      It would be necessary to screen the solubility to determine an appropriate concentration.

      Helpful?

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