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Sethoxydim

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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About This Item

Empirical Formula (Hill Notation):
C17H29NO3S
CAS Number:
Molecular Weight:
327.48
Beilstein:
8222943
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

−20°C

SMILES string

CCC\C(=N/OCC)C1=C(O)CC(CC(C)SCC)CC1=O

InChI

1S/C17H29NO3S/c1-5-8-14(18-21-6-2)17-15(19)10-13(11-16(17)20)9-12(4)22-7-3/h12-13,19H,5-11H2,1-4H3/b18-14+

InChI key

CSPPKDPQLUUTND-NBVRZTHBSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma aldrich.com

Sethoxydim is a selective, systemic, and cyclohexanedione oxime herbicide, absorbed mainly by foliage, and, to a lesser extent, by roots. It is an acetyl CoA carboxylase (ACCase) inhibitor, which inhibits the incorporation of acetate into fatty acids and interferes with the formation of phospholipids used in building new membranes. It is used to control annual and perennial grass weeds (except Poa spp.) in broad-leaved crops, including cotton, oilseed rape, soybeans, sugar beets, fodder beets, sunflowers, spinach, potatoes, tobacco, peanuts, strawberries, alfalfa, flax, and vegetables.
Sethoxydim is not approved for use in the European Union (EU) as a plant protection agent, following Regulation (EC) No. 1107/2009 and repealing Directive 91/414/EEC. But maximum residue levels of 0.05 mg/kg to 10 mg/kg are allowed for the presence of sethoxydim, expressed as a sum of sethoxydim and clethodim including their degradation products, in products of plant and animal origin, according to the EU Reg. No 839/2008.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Sethoxydim CRM may also be used as given below:

  • Simultaneous residue analysis of 379 pesticides in human serum samples using the QuEChERS extraction method and liquid chromatography-tandem mass spectrometry (LC-MS/MS)
  • Method development for multi-residue analysis of pesticides in agricultural water samples, extracted by QuEChERS method using liquid chromatography (LC) with mass spectrometry (MS)
  • Determination of 260 pesticide residues in human urine samples using a scaled-down QuEChERS approach for sample extraction and liquid chromatography-tandem mass spectrometry (LC-MS/MS)
  • Evaluation of liquid chromatography high-resolution mass spectrometry (UHPLC-HRMS) using time-of-flight mass spectrometry as an accurate-mass multi-residue screening method to estimate multi-class organic contaminants in baby food samples
  • Development of a semi-automated method for the analysis of 261 pesticides and 41 environmental contaminants in catfish muscle samples by QuEChERS sample extraction and low pressure-GC-MS/MS and UHPLC-MS/MS, following an automated robotic micro-SPE clean-up
  • Multi-residue analysis of 200 pesticides and 65 environmental contaminants in 10 samples of cattle, swine, and chicken muscles by fast low-pressure gas chromatography (LP-GC-MS/MS) and ultrahigh-performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS)

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Chronic 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Yongho Shin et al.
Journal of agricultural and food chemistry, 66(13), 3550-3560 (2018-03-15)
A screening method for simultaneous analysis of 379 pesticides in human serum was developed using liquid chromatography-tandem mass spectrometry (LC-MS/MS). Electrospray ionization with positive/negative switching mode of LC-MS/MS was adopted, and scheduled multiple reaction monitoring for each target compound was
Development and application of a multi-residue method to determine pesticides in agricultural water using quechers extraction and lc-ms/ms analysis
Song NH, et al.
Separations, 7(4), 52-52 (2020)
Lijun Han et al.
Food chemistry, 319, 126592-126592 (2020-03-21)
A fast, fit-for-purpose, high-throughput method was developed and validated for the analysis of 302 targeted contaminants in catfish muscle. Targeted contaminants included pesticides and metabolites with US regulatory levels, plus other lipophilic pesticides and environmental contaminants: PAHs, PCBs, PBDEs and

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