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About This Item
Linear Formula:
CH3OC6H4CH=CHNO2
CAS Number:
Molecular Weight:
179.17
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
mp
86-88 °C (lit.)
solubility
chloroform: soluble 25 mg/mL, clear, yellow
SMILES string
[H]\C(=C(\[H])[N+]([O-])=O)c1ccc(OC)cc1
InChI
1S/C9H9NO3/c1-13-9-4-2-8(3-5-9)6-7-10(11)12/h2-7H,1H3/b7-6+
InChI key
JKQUXSHVQGBODD-VOTSOKGWSA-N
Related Categories
General description
trans-4-Methoxy-β-nitrostyrene participates in the Michael reaction on carbapenam intermediate.
Application
trans-4-Methoxy-β-nitrostyrene acts as guest molecule and forms guest molecules forming co-crystal phases with the d-form of robust syndiotactic polystyrene (sPS). It may be employed as a Michael acceptor in the synthesis of proline based chiral ionic liquid catalysts with two five-membered unsaturated aza-heterocycles.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Polymer co-crystalline films for photonics.
Daniel C, et al.
Journal of the European Optical Society: Rapid Publications, 4 (2009)
Proline Based Chiral Ionic Liquids for Enantioselective Michael Reaction.
Nobuoka K, et al.
Organic Chemistry International (2014)
Sachin A Pawar et al.
Organic & biomolecular chemistry, 11(48), 8294-8297 (2013-11-13)
Herein, we report the development of mild, organocatalyzed routes to novel carbapenam derivatives through aldol, Mannich and Michael C-C bond forming reactions.
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