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723150

Sigma-Aldrich

2-Hydroxyethyl 2-bromoisobutyrate

95%

Synonym(s):

ATRP hydroxy initiator, HEBIB, HO-BriBu

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About This Item

Empirical Formula (Hill Notation):
C6H11BrO3
CAS Number:
189324-13-8
Molecular Weight:
211.05
MDL number:
MFCD16621490
UNSPSC Code:
12162002
PubChem Substance ID:
329763981
NACRES:
NA.23

Assay

95%

form

liquid

refractive index

n20/D 1.476

density

1.456 g/mL at 25 °C

SMILES string

CC(C)(Br)C(=O)OCCO

InChI

1S/C6H11BrO3/c1-6(2,7)5(9)10-4-3-8/h8H,3-4H2,1-2H3

InChI key

MHXMVFDLNGKBSR-UHFFFAOYSA-N

Application

ATRP for Everyone: Ligands and Initiators for the Clean Synthesis of Functional Polymers
Atom Transfer Radical Polymerization (ATRP) initiator for the creation of hydroxy functionalized telechelic polymers. Can be used to modify carboxylate- or isocyanate- modified surfaces, particles or biomolecules.

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Product No.
Description
Pricing

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H318

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Ethyl α-bromophenylacetate 97%

Sigma-Aldrich

554065

Ethyl α-bromophenylacetate

Abhispa Sahu et al.
Ultrasonics sonochemistry, 67, 105163-105163 (2020-05-18)
This paper reports on sonochemically catalyzed atom transfer radical polymerization (SONO-ATRP) polyelectrolyte synthesis and chain-end functionalization to single-walled carbon nanotubes (SWCNT). This all aqueous process is kinetically facile without use of initiator, or reducing agents and with very low concentrations
Coessens, V.; Pintauer, T.; Matyjaszewski, K.
Progress in Polymer Science, 26, 337-337 (2001)
Jingli Chen et al.
Theranostics, 7(17), 4149-4167 (2017-11-22)
Currently unsatisfactory treatment of myocardial infarction (MI) is due to the unbridled inflammation and the delayed diagnosis at the early stage. To address these problems, firstly, phosphatidylserine (PS) was used to modulate the phenotypes of macrophages (MΦ) and resolve the
"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.
Nicolay V Tsarevsky et al.
Chemical reviews, 107(6), 2270-2299 (2007-05-29)
Atom transfer radical polymerization.
K Matyjaszewski et al.
Chemical reviews, 101(9), 2921-2990 (2001-12-26)
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ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

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Protocols

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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