CRM06035
Benfuracarb
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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About This Item
Empirical Formula (Hill Notation):
C20H30N2O5S
CAS Number:
Molecular Weight:
410.53
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24
Recommended Products
grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
storage temp.
−20°C
SMILES string
CCOC(=O)CCN(SN(C)C(=O)Oc1cccc2CC(C)(C)Oc12)C(C)C
InChI
1S/C20H30N2O5S/c1-7-25-17(23)11-12-22(14(2)3)28-21(6)19(24)26-16-10-8-9-15-13-20(4,5)27-18(15)16/h8-10,14H,7,11-13H2,1-6H3
InChI key
FYZBOYWSHKHDMT-UHFFFAOYSA-N
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Benfuracarb is a carbamate insecticide, widely used to protect citrus fruits, maize, sugar beets, and other vegetables against insect pests. It inhibits the activity of the acetylcholinesterase enzyme and prevents the hydrolysis of acetylcholine to choline and acetic acid.
On application, benfuracarb is rapidly converted to its primary metabolite carbofuran. Therefore, benfuracarb is reported as carbofuran, which includes the sum of carbofuran (including carbofuran originating from carbosulfan, benfuracarb, or furathiocarb) and 3-OH carbofuran. Carbofuran is not allowed for use in European Union and a default maximum residue limit (MRL) of 0.01 mg/kg and 0.02 mg/kg is set for its presence in frozen/fresh fruits and tree nuts respectively according to the Regulation (EC) no. 2015/399.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Benfuracarb is a carbamate insecticide, widely used to protect citrus fruits, maize, sugar beets, and other vegetables against insect pests. It inhibits the activity of the acetylcholinesterase enzyme and prevents the hydrolysis of acetylcholine to choline and acetic acid.
On application, benfuracarb is rapidly converted to its primary metabolite carbofuran. Therefore, benfuracarb is reported as carbofuran, which includes the sum of carbofuran (including carbofuran originating from carbosulfan, benfuracarb, or furathiocarb) and 3-OH carbofuran. Carbofuran is not allowed for use in European Union and a default maximum residue limit (MRL) of 0.01 mg/kg and 0.02 mg/kg is set for its presence in frozen/fresh fruits and tree nuts respectively according to the Regulation (EC) no. 2015/399.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Benfuracarb certified reference material (CRM) may also be used as following:
Benfuracarb certified reference material (CRM) may also be used as following:
- Residue analysis of 18 insecticides in water and sediment samples collected from aquatic areas around the rice paddy fields by chromatography tandem mass spectrometry
- Analysis of 168 pesticides in paprika using the modified dry ice-partitioning QuEChERS method combined with LC-MS/MS
- Simultaneous determination of 18 carbamate pesticide residues from whole chestnut and pine nut samples using ultra-performance liquid chromatography coupled with tandem mass spectrometry (UPLC-MS-MS) following a gel permeation chromatography (GPC) clean-up
- Development and validation of a multi-residue analysis method for detecting 70 pesticides belonging to different classes from drinking water samples using a polymeric sorbent for solid phase extraction (SPE) and gas and liquid chromatography coupled to tandem mass spectrometry (GC-MS/MS and LC-MS/MS) for quantification
- Detection of 15 organic nitrogen-containing pesticides from vegetable samples using matrix solid-phase dispersion (MSPD) along with gas chromatography-Tandem mass spectrometry (GC-MS-MS)
- Simultaneous analysis of 27 organophosphorus, organochlorine, pyrethroid, and carbamate pesticides in Radix astragali by microwave-assisted or dispersive-solid phase extraction in combination with GC-MS
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
>212.0 °F
Flash Point(C)
> 100 °C
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Xuejin Mao et al.
Talanta, 97, 131-141 (2012-07-31)
A simple, rapid and reliable method was proposed for the simultaneous determination of 27 pesticides (organophosphorus, organochlorine, pyrethroid and carbamate pesticides) in Radix astragali. The pesticides were extracted by acetonitrile and the experimental variables, such as temperature, extraction time and
MSPD- GC- MS- MS determination of residues of 15 organic nitrogen-containing pesticides in vegetables
Lin Q, et al.
Chromatographia, 72(11), 1143- 1148 (2010)
Shunsuke Furihata et al.
Environmental pollution (Barking, Essex : 1987), 251, 628-638 (2019-05-21)
The ecological impacts of insecticides in aquatic areas around agricultural lands have long been ignored in the regulation scheme of pesticides in Japan. Upon the scheme, the predicted concentration of an insecticide in the main stream of a river is
Sung Woo Lee et al.
Journal of chromatography. A, 1218(28), 4366-4377 (2011-06-03)
This study describes a new QuEChERS method referred to as the dry ice-partitioning QuEChERS method. This current method can be differentiated from the other QuEChERS methods in the sense that it uses dry ice rather than salts or buffers to
Yasin Eren et al.
Cytotechnology, 68(4), 637-643 (2014-11-09)
Benfuracarb is a carbamate insecticide used to control insect pests in vegetables and it has anti-acetylcholinesterase activity lower than other carbamates. Cytotoxic effects of benfuracarb were evaluated by using root growth inhibition (EC50), mitotic index (MI), and mitotic phase determinations
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