Magnesium oxide is a mild basic reagent used in acylations, alkylations, oxidations, reductions, formation of heterocycles, ring-opening of tertiary amines, nitration of aromatic acetals, hydrohalogenation, dehydrohalogenation, carbonylation of organomercurials, and serves as a leaving group to form alkenes.
Application
Magnesium oxide can be used as a catalyst in the:
Dehydrogenation of n-octane to synthesize octenes.
Solvent-free Knoevenagel condensation of aromatic aldehydes and ethyl cyanoacetate to synthesize electrophilic olefins.
Journal of the American Chemical Society, 134(43), 18109-18115 (2012-10-05)
Adsorbed molecules are involved in many reactions on solid surface that are of great technological importance. As such, there has been tremendous effort worldwide to learn how to predict reaction rates and equilibrium constants for reactions involving adsorbed molecules. Theoretical
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