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185841

Sigma-Aldrich

Dicyclohexylamine

99%

Synonym(s):

Aminodicyclohexane, Bis(cyclohexyl)amine, Dodecahydrodiphenylamine, N,N-Dicyclohexylamine, N-Cyclohexylcyclohexanamine

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About This Item

Linear Formula:
(C6H11)2NH
CAS Number:
101-83-7
Molecular Weight:
181.32
Beilstein:
605923
EC Number:
202-980-7
MDL number:
MFCD00011658
UNSPSC Code:
12352100
eCl@ss:
39030438
PubChem Substance ID:
24851183
NACRES:
NA.22

vapor density

6 (vs air)

vapor pressure

12 mmHg ( 37.7 °C)

Assay

99%

form

liquid

refractive index

n20/D 1.484 (lit.)

bp

117-120 °C/10 mmHg
256 °C (lit.)

mp

−2 °C (lit.)

solubility

organic solvents: soluble
water: very slightly soluble

density

0.912 g/mL at 20 °C (lit.)

SMILES string

C1CCC(CC1)NC2CCCCC2

InChI

1S/C12H23N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h11-13H,1-10H2

InChI key

XBPCUCUWBYBCDP-UHFFFAOYSA-N

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Application

Dicyclohexylamine was used to constitute ionic liquid matrices for bacterial analysis in matrix assisted laser desorption/ionisation mass spectrometry. It was used to develop a new palladium catalyst for Suzuki coupling reaction of aryl bromides with boronic acids. It was used as extractant in determination of gold(III) by dispersive liquid-liquid microextraction and electrothermal atomic absorption spectrometry.

Signal Word

Danger

Hazard Statements

H301 + H311,H314,H410

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Corr. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

204.8 °F - closed cup

Flash Point(C)

96 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Shigehiro Kagaya et al.
Talanta, 80(3), 1364-1370 (2009-12-17)
A combined method with dispersive liquid-liquid microextraction (DLLME) and electrothermal atomic absorption spectrometry (ETAAS) has been developed for determining gold(III). Dicyclohexylamine, a new extractant for gold(III), showed excellent performance in DLLME. Acetone was indispensable to the quantitative extraction of gold(III)
Bin Tao et al.
The Journal of organic chemistry, 69(13), 4330-4335 (2004-06-19)
A new palladium catalyst (DAPCy) made from Pd(OAc)(2) and commercially available, inexpensive dicyclohexylamine has been developed for the Suzuki coupling reaction of aryl bromides with boronic acids to give the coupling products in good to high yields. The air-stable catalyst
A F Tiburcio et al.
Plant cell, tissue and organ culture, 9, 111-120 (1987-01-01)
We studied the effects of inhibitors of ornithine decarboxylase (ODC), arginine decarboxylase (ADC) and spermidine synthase (Spd synthase) on organogenesis and the titers of polyamines (PA) and alkaloids in tobacco calli. DL-alpha-diffluromethylarginine (DFMA) and D-arginine (D-Arg), both inhibitors of ADC
Erol Erçağ et al.
Talanta, 78(3), 772-780 (2009-03-10)
Because of the extremely heterogeneous distribution of explosives in contaminated soils, on-site colorimetric methods are efficient tools to assess the nature and extent of contamination. To meet the need for rapid and low-cost chemical sensing of explosive traces or residues
L Paulin et al.
Antonie van Leeuwenhoek, 52(6), 483-490 (1986-01-01)
Dicyclohexylamine, which is an inhibitor of bacterial and mammalian spermidine synthase, greatly inhibited the synthesis of spermidine in Pseudomonas aeruginosa. The depletion of spermidine caused by dicyclohexylamine was accompanied by an inhibition of growth of bacteria. This inhibition was reversed
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