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669431

Sigma-Aldrich

Lithium fluoride

Precipitated, 99.995%

Synonym(s):

Fluorolithium

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About This Item

Linear Formula:
LiF
CAS Number:
Molecular Weight:
25.94
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.995%

form

powder

impurities

≤55.0 ppm Trace Metal Analysis

mp

845 °C (lit.)

density

2.64 g/mL at 25 °C (lit.)

SMILES string

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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General description

Lithium fluoride is an inorganic halide with good ionic conductivity, high refractive index, and high transmittance in the UV region. Owing to its unique properties, it is widely used in the field of optical and electronic devices, X-ray imaging, and dental materials.

Application

Lithium fluoride(LiF) can be used:
  • To fabricate an insulating layer in AC-driven organic light-emitting diodes(OLEDs). LiF provides excellent capacitance and high stability to the insulating layers in AC devices.
  • As a precursor to synthesize Eu2+/Ce3+ doped barium lithium fluoride phosphors by solvothermal method.
  • To fabricate LiF thin film coating on the lithium anodes to enhance their stability and coulombic efficiency.
  • As an additive to enrich and enhance the performance of solidelectrolyte interface(SEI) in Li metal batteries.

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Novel ALD Chemistry Enabled Low-Temperature Synthesis of Lithium Fluoride Coatings for Durable Lithium Anodes
Lin Chen, et al.
ACS Applied Materials & Interfaces, 10, 26972-26981 (2018)
Alternating current driven organic light emitting diodes using lithium fluoride insulating layers
Shang-Yi Liu, et al.
Scientific Reports, 4, 7559-7559 (2014)
Solvothermal fabrication and luminescent properties of Eu2+/Ce3+ doped barium lithium fluoride
Guoxian ZHU, et al.
Journal of Rare Earths, 30, 985-989 (2012)
The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium
Mingfu He, et al.
Proceedings of the National Academy of Sciences, 117, 73-79 (2020)
R Takam et al.
Radiation protection dosimetry, 150(1), 22-33 (2011-08-30)
(6)LiF:Mg,Cu,P and (7)LiF:Mg,Cu,P glass-rod thermoluminescent dosemeters (TLDs) were used for measurements of out-of-field photon and neutron doses produced by Varian iX linear accelerator. Both TLDs were calibrated using 18-MV X-ray beam to investigate their dose-response sensitivity and linearity. CR-39 etch-track

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