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902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

≥95%, powder

Synonym(s):

Photocatalyst

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About This Item

Empirical Formula (Hill Notation):
C36H22F16IrN4P
CAS Number:
2229858-27-7
Molecular Weight:
1037.75
MDL number:
MFCD32857514
UNSPSC Code:
12161602
NACRES:
NA.22

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Product Name

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%

assay

≥95%

form

powder

reaction suitability

core: iridium, reaction type: Photocatalysis, reagent type: catalyst

mp

>300 °C

SMILES string

FC1=CC(F)=C2C3=CC=C(C=[N]3[Ir+3]45([C-]2=C1)([C-]6=CC(F)=CC(F)=C6C7=CC=C(C=[N]74)C)[N]8=CC=C(C=C8C=9C=C(C=C[N]95)C(F)(F)F)C(F)(F)F)C.[F-][P+5]([F-])([F-])([F-])([F-])[F-]

InChI

InChI=1S/C12H6F6N2.2C12H8F2N.F6P.Ir/c13-11(14,15)7-1-3-19-9(5-7)10-6-8(2-4-20-10)12(16,17)18;2*1-8-2-5-12(15-7-8)10-4-3-9(13)6-11(10)14;1-7(2,3,4,5)6;/h1-6H;2*2-3,5-7H,1H3;;/q;3*-1;+3

InChI key

RYKRFKQFYGHADE-UHFFFAOYSA-N

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1 of 4

This Item
902217908703905917
Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6 ≥95%

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6 ≥95%

Sigma-Aldrich

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 ≥95%

Sigma-Aldrich

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

(Ir[Me(Me)ppy]2(dtbpy))PF6

Sigma-Aldrich

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

assay

≥95%

assay

≥95%

assay

≥95%

assay

-

reaction suitability

core: iridium, reagent type: catalyst, reaction type: Photocatalysis

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

reaction suitability

-

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

form

powder

form

powder or crystals

form

powder or crystals

form

powder

mp

>300 °C

mp

>300 °C

mp

-

mp

-

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

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[Ir(dFppy)2(dtbbpy)]PF6

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Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

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(Ir[Me(Me)ppy]2(dtbpy))PF6

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[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

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[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

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[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

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Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCJ9415

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Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a

Global Trade Item Number

SKUGTIN
902225-500MG04061838635501
902225-100MG04061838635495

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