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902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6

≥95%, powder or crystals

Synonym(s):

Ir photocatalyst, Photocatalyst

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$143.00

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$680.00

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About This Item

Empirical Formula (Hill Notation):
C34H16F18IrN4P
CAS Number:
2030437-92-2
Molecular Weight:
1045.68
MDL number:
MFCD27952560
UNSPSC Code:
12161600
NACRES:
NA.22

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Product Name

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

450 nm

SMILES string

[Ir+]741([NH]8=C(c9c7cc(cc9F)F)C=CC(=C8)F)([NH]5=CC(=CC=C5c6c4cc(cc6F)F)F)[NH]2=CC=C(C=C2C3=CC(=CC=[NH]31)C(F)(F)F)C(F)(F)F.F[P-](F)(F)(F)(F)F

InChI key

UCNIZYCFAFBGQB-UHFFFAOYSA-N

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1 of 4

This Item
902225908568905917
Ir[dFFppy]2-(4,4′-dCF3bpy)PF6 ≥95%

Sigma-Aldrich

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6 ≥95%

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%

Sigma-Aldrich

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6

(Ir[Me(Me)ppy]2(dtbpy))PF6

Sigma-Aldrich

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

assay

≥95%

assay

≥95%

assay

≥95%

assay

-

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

reaction suitability

core: iridium, reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

-

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

form

powder or crystals

form

powder

form

powder or crystals

form

powder

mp

>300 °C

mp

>300 °C

mp

>300 °C

mp

-

photocatalyst activation

450 nm

photocatalyst activation

-

photocatalyst activation

460 nm

photocatalyst activation

465 nm

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

related product

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747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

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Ir(dFppy)3

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Ir[p-F(t-Bu)-ppy]3

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(S)-2-Benzylpiperidine, ≥95%

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Mes-Umemoto reagent, ≥95%

901368

[Ir(dFppy)2(dtbbpy)]PF6

901409

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%

902489

Tris(trimethylsilyl)silanol, ≥95%

902802

2-(2,4-Difluorophenyl)-5-fluoropyridine, ≥95%

902810

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902829

2-(2,4-Difluorophenyl)-5-methylpyridine, ≥95%

904694

Ir(p-CF3-ppy)3, ≥95%

905518

Ir(dFFppy)2(dtbbpy)PF6

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

925497

[Ir(dFOMeppy)2(dtbbpy)]PF6, ≥95%

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW9164
MKCP8383
MKCS6906
MKCK3266

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Gilbert J Choi et al.
Nature, 539(7628), 268-271 (2016-11-04)
Despite advances in hydrogen atom transfer (HAT) catalysis, there are currently no molecular HAT catalysts that are capable of homolysing the strong nitrogen-hydrogen (N-H) bonds of N-alkyl amides. The motivation to develop amide homolysis protocols stems from the utility of
Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a

Global Trade Item Number

SKUGTIN
902217-100MG04061838635457
902217-500MG04061838635464

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