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751618

MorDalphos

97%, solid

Synonym(s):

Di(1-adamantyl)-2-morpholinophenylphosphine

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Pack SizeSKUAvailabilityPrice
250 mg
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$99.50
1 g
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$378.00
$283.50
5 g
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$1,110.00

About This Item

Empirical Formula (Hill Notation):
C30H42NOP
CAS Number:
Molecular Weight:
463.63
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:

$99.50


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Product Name

MorDalphos, 97%

Quality Level

product line

Buchwald Ligand

assay

97%

form

solid

reaction suitability

reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

mp

219-224 °C

functional group

phosphine

storage temp.

2-8°C

SMILES string

C1CN(CCO1)c2ccccc2P([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7

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This Item
751413791016695262
functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

reaction suitability

reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

-

reaction suitability

reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

form

solid

form

solid

form

solid

form

solid

assay

97%

assay

98%

assay

97%

assay

97%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

storage temp.

2-8°C

storage temp.

-

storage temp.

15-25°C

storage temp.

-

Application

MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.

related product

Product No.
Description
Pricing

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Rational and Predictable Chemoselective Synthesis of Oligoamines via Buchwald?Hartwig Amination of (Hetero) Aryl Chlorides Employing Mor-DalPhos.
Tardiff B, et al.
The Journal of Organic Chemistry, 77(2), 1056-1071 (2011)
Palladium-catalyzed mono-?-arylation of acetone with aryl halides and tosylates.
Hesp K D, et al.
Journal of the American Chemical Society, 133(14), 5194-5197 (2011)
Stereo-and regioselective gold-catalyzed hydroamination of internal alkynes with dialkylamines.
Hesp K D, et al.
Journal of the American Chemical Society, 132(51), 18026-18029 (2010)
AP, N?Ligand for Palladium?Catalyzed Ammonia Arylation: Coupling of Deactivated Aryl Chlorides, Chemoselective Arylations, and Room Temperature Reactions
Lundgren R J, et al.
Angewandte Chemie (International Edition in English), 122(24), 4165-4168 (2010)

Articles

DalPhos ligands enable Pd-catalyzed C-N and C-C bond formation with good functional group tolerance.

Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.

Related Content

Explore reliable, premium grade catalysis materials for your pharma or industrial project. Specialty chemicals and formulations are available in bulk quantities and volumes from a few grams to multi-metric tons with complete documentation to simplify your leap from development to commercialization.

Stradiotto group focuses on electronically rich ligands for late metal catalysis, including Pd and Au chemistry applications.

Phosphine Ligand Application Guide

Global Trade Item Number

SKUGTIN
751618-5G04061833331910
751618-250MG04061833230046
751618-1G04061826645925

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