Yes, the item 186171-4X25ML comes in a Sure/Seal™ glass bottle.
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
50 mL | Available to ship TODAYfromMILWAUKEE | $44.80 |
100 mL | Available to ship TODAYfromMILWAUKEE | $72.00 |
4 x 25 mL | Available to ship TODAYfromMILWAUKEE | $72.70 |
800 mL | Available to ship TODAYfromMILWAUKEE | $190.00 |
4 x 100 mL | Available to ship TODAYfromMILWAUKEE | $197.00 $167.45 |
8 L | Available to ship TODAYfromSHEBOYGAN FALLS | $1,030.00 |
18 L | Check Cart for Availability | $1,850.00 |
About This Item
form
liquid
Quality Segment
concentration
1.6 M in hexanes
density
0.68 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]CCCC
InChI
1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;
InChI key
MZRVEZGGRBJDDB-UHFFFAOYSA-N
Application
- Copolymerization of butadiene and styrene under the influence of n-butyllithium: This study explores the copolymerization process using n-butyllithium as a catalyst, which is significant for the development of new synthetic rubber materials (V Bronskaya et al., 2023).
- Modifiers of n-Butyllithium in the Synthesis of Polybutadiene and Styrene-Butadiene Rubbers: Explores the use of n-butyllithium with different modifiers in the synthesis of industrial rubbers, important for understanding the control of polymer properties (VS Glukhovskoi et al., 2014).
- Aggregation and Solvation of n-Butyllithium: Examines the aggregation behavior and solvation properties of n-butyllithium in various solvents, providing insights into its chemical interactions essential for organic synthesis (O Tai et al., 2017).
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Other Notes
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| description 1.6 M in hexanes | description 1.4 M in cyclohexane | description 2.7 M in heptane | description 2.0 M in cyclohexane |
| concentration 1.6 M in hexanes | concentration 1.4 M in cyclohexane | concentration 2.7 M in heptane | concentration 2.0 M in cyclohexane |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 200 |
| form liquid | form liquid | form liquid | form liquid |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
| density 0.68 g/mL at 25 °C | density 0.769 g/mL at 25 °C | density 0.71 g/mL at 20 °C | density 0.775 g/mL at 25 °C |
ACS grade Butyllithium solution | - | - | - |
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signalword
Danger
target_organs
Central nervous system
supp_hazards
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
flash_point_f
-14.8 °F - closed cup
flash_point_c
-26 °C - closed cup
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 - STOT SE 3 - Water-react. 1
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Is the default container for an individual 25 mL bottle from 186171-4X25ML a sure seal bottle? Or does the the sure seal bottle need to be specially requested? i.e. does ordering 186171-4X25ML mean you will get your four bottles with sure-seal septa?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdfHelpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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How are the 100 mL, 800 mL, and 1 L unit sizes of Product 186171, Butyllithium solution, packaged?
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They are packaged in our Sure-Seal™ bottle, which have a crown cap with a PTFE/elastomer liner crimped into place.
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Is it necessary to handle Product 186171, Butyllithium solution, under inert atmosphere?
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This product ignites on exposure to air and should be handled under inert atmosphere such as under nitrogen.
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How are the 8 L and 18 L unit sizes of Product 186171, Butyllithium solution, packaged?
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They are packaged in our Kilo-Lab™ cylinder.
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What should I do if precipitate is present in Product 186171, Butyllithium solution?
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Haziness may form upon storage but does not affect the specification. If precipitation is present, then gently mix precipitate back into solution under an inert atmosphere.
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What are common uses for Product 186171, Butyllithium solution?
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Butyllithium is widely use as a polymerization initiator in the production of elastomers such as polybutadiene or styrene-butadiene-styrene (SBS). It is also broadly employed as a strong base (superbase) in organic synthesis, both industrially and in the laboratory.
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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