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Bromochloromethane

analytical standard

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About This Item

Linear Formula:
BrCH2Cl
CAS Number:
74-97-5
Molecular Weight:
129.38
Beilstein/REAXYS Number:
1730801
EC Number:
200-826-3
MDL number:
MFCD00000880
UNSPSC Code:
12000000
PubChem Substance ID:
24867875

grade

analytical standard

vapor density

4.5 (vs air)

vapor pressure

117 mmHg ( 20 °C)

CofA

current certificate can be downloaded

packaging

ampule of 500 mg

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.482 (lit.)

bp

68 °C (lit.)

mp

−88 °C (lit.)

density

1.991 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

storage temp.

2-30°C

SMILES string

ClCBr

InChI

1S/CH2BrCl/c2-1-3/h1H2

InChI key

JPOXNPPZZKNXOV-UHFFFAOYSA-N

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General description

Sigma-Aldrich offers bromochloromethane for a broad-range applications such as environmental, food and beverage, forensics, petrochemical and pharmaceutical analyzes.

Application

Bromochloromethane has been used in form of an internal standard mixture, for the identification and separation of volatile organic compounds emitted from several sources, using gas chromatography coupled with mass spectrometry (GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Ozone 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
LRAD3094
LRAC3891
LRAC0519
LC26020V
LC18174V

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Volatile Profiles of Emissions from Different Activities Analyzed Using Canister Samplers and Gas Chromatography-Mass Spectrometry (GC/MS) Analysis: A Case Study
Orecchio S, et al.
International Journal of Environmental Research and Public Health, 14, 195-195 (2017)
Juan Li et al.
The Journal of chemical physics, 126(18), 184304-184304 (2007-05-19)
The pulsed field ionization-photoelectron (PFI-PE) spectrum of bromochloromethane (CH2BrCl) in the region of 85,320-88,200 cm-1 has been measured using vacuum ultraviolet laser. The vibrational structure resolved in the PFI-PE spectrum was assigned based on ab initio quantum chemical calculations and
M L Gargas et al.
Toxicology and applied pharmacology, 86(3), 341-352 (1986-12-01)
In vivo metabolic constants were determined in male Fischer rats for five chemicals: 1,1-dichloroethylene (1,1-DCE), diethyl ether (DE), bromochloromethane (BCM), methyl chloroform (MC), and carbon tetrachloride (CCl4). A closed recirculated exposure system was used to collect a series of uptake
R Thier et al.
Proceedings of the National Academy of Sciences of the United States of America, 90(18), 8576-8580 (1993-09-15)
Dihalomethanes can produce liver tumors in mice but not in rats, and concern exists about the risk of these compounds to humans. Glutathione (GSH) conjugation of dihalomethanes has been considered to be a critical event in the bioactivation process, and
Gunjan Goel et al.
The British journal of nutrition, 101(10), 1484-1492 (2009-02-27)
Bromochloromethane (BCM), a halogenated methane analogue, was evaluated for its anti-methanogenic activity in both batch and continuous fermentation systems. For batch fermentation, a roughage-based substrate was incubated with mixed rumen microflora for 24 h at two concentrations of BCM (5
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