18649
Silicon dioxide
acid washed
Synonym(s):
Cristobalite, Quartz, Sand, Silica
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About This Item
Linear Formula:
SiO2
CAS Number:
Molecular Weight:
60.08
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
SB.52
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form
solid
quality
acid washed
impurities
≤0.01% in acid soluble iron (Fe)
≤0.5% soluble in HCl
loss
≤0.5% loss on ignition, 800 °C
refractive index
n20/D 1.544 (lit.)
mp
1610 °C (lit.)
density
2.6 g/mL at 25 °C (lit.)
anion traces
chloride (Cl-): ≤100 mg/kg
SMILES string
O=[Si]=O
InChI
1S/O2Si/c1-3-2
InChI key
VYPSYNLAJGMNEJ-UHFFFAOYSA-N
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General description
Silicon dioxide (SiO2) exists in three crystalline forms, namely quartz, tridymite and cristobalite. It reacts with hydrofluoric acid to form silicon tetrafluoride (SiF4) and water. Silicates are formed on reacting SiO2 with alkali melts. SiO2 is the main component in glass, brick and concrete and also forms the insulator in silicon devices. The alteration of the surface of SiO2 with (3-aminopropyl)triethoxysilane (APTES) for binding lactate dehydrogenase (LDH) to form an amino layer has been reported. The silicon-silicon dioxide structure has been investigated at liquid nitrogen temperature by electron spin resonance spectra.
Application
Silicon dioxide may be used to produce silicon by electrochemical reduction in the presence of calcium chloride (CaCl2) electrolyte. It may also be used to prepare FeCl3/SiO2, a supported reagent for the oxidative coupling reactions.
Storage Class
11 - Combustible Solids
wgk_germany
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Iron trichloride/silicon dioxide reacts as oxidant or Lewis acid with phenol ethers.
Jempty TC, et al.
The Journal of Organic Chemistry, 46(22), 4545-4551 (1981)
Study of silicon-silicon dioxide structure by electron spin resonance I.
Nishi Y.
Japanese Journal of Applied Physics, 10(1), 52-52 (1971)
Pinpoint and bulk electrochemical reduction of insulating silicon dioxide to silicon.
Nohira T, et al.
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Electronic structure of silicon dioxide (a review).
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Surface modification of silicon dioxide, silicon nitride and titanium oxynitride for lactate dehydrogenase immobilization.
Saengdee P, et al.
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