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62136

Supelco

(+)-trans-Limonene 1,2-epoxide

analytical standard

Synonym(s):

(+)-trans-p-Mentha-1,8-diene 1,2-epoxide, (1S,2R,4R)-4-Isopropenyl-1-methyl-1-cyclohexene 1,2-epoxide, (1S,4R)-1,2-Epoxy-p-menth-8-ene

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About This Item

Empirical Formula (Hill Notation):
C10H16O
CAS Number:
6909-30-4
Molecular Weight:
152.23
Beilstein/REAXYS Number:
80940
MDL number:
MFCD16652609
UNSPSC Code:
85151701
PubChem Substance ID:
329759712
NACRES:
NA.24

grade

analytical standard

assay

≥95.0% (sum of enantiomers, GC)

optical activity

[α]20/D +90±2°, neat

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.466

density

0.930 g/mL at 20 °C (lit.)

application(s)

food and beverages

format

neat

storage temp.

2-8°C

SMILES string

CC([C@@H]1CC[C@@]2(C)[C@@](O2)([H])C1)=C

InChI

1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9-,10+/m1/s1

InChI key

CCEFMUBVSUDRLG-BBBLOLIVSA-N

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

149.0 °F - closed cup

flash_point_c

65 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF7072
BCBZ5646
BCBS7505V
BCBT0145

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J W Regan et al.
Xenobiotica; the fate of foreign compounds in biological systems, 10(12), 859-861 (1980-12-01)
1. The metabolism of limonene-1,2-epoxide was studied following intraperitoneal injection in rats and in rat liver homogenates. 2. Limonene-1,2-glycol was the only neutral metabolite detected. Major limonene metabolites, p-mentha-2,8-dien-1-alpha and -beta-ol and p-mentha-1,8-dien-6-alpha and -beta-ol were not observed. 3. Limonene-1,2-epoxide
M J van der Werf et al.
Journal of bacteriology, 180(19), 5052-5057 (1998-09-28)
An epoxide hydrolase from Rhodococcus erythropolis DCL14 catalyzes the hydrolysis of limonene-1,2-epoxide to limonene-1,2-diol. The enzyme is induced when R. erythropolis is grown on monoterpenes, reflecting its role in the limonene degradation pathway of this microorganism. Limonene-1,2-epoxide hydrolase was purified
T A Metts et al.
Indoor air, 17(5), 362-371 (2007-09-21)
If released in significant amounts, products formed by reactions between ozone (O3) and volatile organic compounds (VOCs) sorbed on activated carbon (AC) filters could degrade indoor air quality (IAQ). Heterogeneous reactions were investigated in laboratory experiments aimed at characterizing reaction
L D Lehman-McKeeman et al.
Toxicology and applied pharmacology, 103(3), 539-548 (1990-05-01)
A diverse group of chemicals cause a male rat-specific nephrotoxicity in which alpha 2u-globulin accumulates in renal lysosomes. It has been suggested that these chemicals bind to the protein and decrease its degradation by lysosomal proteinases. To test this hypothesis
Juan Ramón Avilés Moreno et al.
Physical chemistry chemical physics : PCCP, 11(14), 2459-2467 (2009-03-28)
S-(-)-Limonene oxide (4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptane) is a secondary metabolite and an atmospheric pollutant product of oxidation of other terpenes, such as limonene and alpha-pinene, among others. For the first time, a theoretical study of the molecular structure and a theoretical and experimental
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