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46001

Supelco

Benoxacor

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C11H11Cl2NO2
CAS Number:
98730-04-2
Molecular Weight:
260.12
Beilstein/REAXYS Number:
4190275
MDL number:
MFCD01311820
UNSPSC Code:
41116107
PubChem Substance ID:
329757047
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CC1COc2ccccc2N1C(=O)C(Cl)Cl

InChI

1S/C11H11Cl2NO2/c1-7-6-16-9-5-3-2-4-8(9)14(7)11(15)10(12)13/h2-5,7,10H,6H2,1H3

InChI key

PFJJMJDEVDLPNE-UHFFFAOYSA-N

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General description

Benoxacor is a dichloroacetamide herbicide safener, used to protect corn against injury from metolachlor. Its role as a safener involves inducing the enzymatic mechanism of chloroacetanilide detoxification in plants.

Application

Benoxacor may be used as a reference standard in the determination of benoxacor in wheat and soil samples using gas chromatography (GC) and high performance liquid chromatography (HPLC).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation markEnvironment
GHS07,GHS09

signalword

Warning

hcodes

H317,H410

Hazard Classifications

Aquatic Chronic 1 - Skin Sens. 1

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
BCCG5125
BCBT8607
SZB7225XV
SZBC101XV
2231X

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Sihong Liu et al.
The Science of the total environment, 761, 143273-143273 (2020-11-17)
Benoxacor, a chiral herbicide safener for S-metolachlor, has been detected in streams. However, the potential risk this poses to aquatic ecosystems is not clear. This study used zebrafish (Danio rerio) embryos as a model to assess the enantioselective toxicity of
G Kocsy et al.
Plant physiology, 127(3), 1147-1156 (2001-11-14)
With the aim of analyzing their protective function against chilling-induced injury, the pools of glutathione and its precursors, cysteine (Cys) and gamma-glutamyl-Cys, were increased in the chilling-sensitive maize (Zea mays) inbred line Penjalinan using a combination of two herbicide safeners.
Daniele Del Buono et al.
Journal of agricultural and food chemistry, 53(11), 4326-4330 (2005-05-26)
Butachlor is a chloroacetanilide herbicide successfully employed in weeding some important crops, and benoxacor is a safening compound able to induce the enzymatic mechanism of chloroacetanilide detoxification in plants. A practical method for a simultaneous detection of butachlor and benoxacor
Purification and characterization of a glutathione S-transferase from benoxacor-treated maize (Zea mays).
Irzyk PG and Fuerst PE
Plant Physiology, 102(3), 803-810 (1993)
Luciano Scarponi et al.
Journal of agricultural and food chemistry, 53(7), 2483-2488 (2005-03-31)
The action of safener benoxacor on the detoxification of terbuthylazine (TBA) in Zea mays and Festuca arundinacea was ascertained by the investigation of the effects of benoxacor on the activity of glutathione-S-transferases (GSTs) in the shoots of the two plant
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