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Supelco

Folpet

PESTANAL®, analytical standard

Synonym(s):

2-(Trichloromethylsulfanyl)isoindole-1,3-dione

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About This Item

Empirical Formula (Hill Notation):
C9H4Cl3NO2S
CAS Number:
133-07-3
Molecular Weight:
296.56
Beilstein/REAXYS Number:
193373
EC Number:
205-088-6
MDL number:
MFCD00047303
UNSPSC Code:
41116107
PubChem Substance ID:
329753988
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

ClC(Cl)(Cl)SN1C(=O)c2ccccc2C1=O

InChI

1S/C9H4Cl3NO2S/c10-9(11,12)16-13-7(14)5-3-1-2-4-6(5)8(13)15/h1-4H

InChI key

HKIOYBQGHSTUDB-UHFFFAOYSA-N

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General description

Folpet is a contact fungicide used for the control of foliar and seed-borne diseases. Folpet is known to inhibit various oxidative enzymes, carboxylases and also enzymes required for phosphate metabolism and citrate synthesis.

Application

Folpet may be used as a reference standard for the determination of the analyte in food matrices based on QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) method for extraction followed by gas chromatography coupled with electron ionization and triple quadrupole mass spectrometry (GC-EI-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL4579
BCCJ0793
BCCD1736
BCCD0436
BCBX4657

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Quantification of folpet and phthalimide in food by gas chromatography and mass spectrometry: Overcoming potential analytical artefacts.
Huertas-Perez JF, et al.
Food Chemistry, 260, 213-220 (2018)
Mercedes Barreda et al.
Journal of AOAC International, 89(4), 1080-1087 (2006-08-19)
A gas chromatography/negative chemical ionization-mass spectrometry (GC/NCI-MS) method has been developed for the simultaneous determination of the fungicides captan and folpet in khaki (persimmon; flesh and peel) and cauliflower. Samples were extracted with acetone in the presence of 0.1 M
Mireille Canal-Raffin et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 865(1-2), 106-113 (2008-03-18)
Solid-phase extractions followed by HPLC-UV/DAD methods were developed for occupational biological monitoring or forensic investigations of the fungicide folpet using its degradation products, phthalimide and phthalamic acid as plasma biomarkers. These methods show good linearity (r>0.9955), precision (CV<15%) and accuracy
Mireille Canal-Raffin et al.
Toxicology, 249(2-3), 160-166 (2008-07-01)
Folpet, a widely used dicarboximide fungicide, has been detected in the ambient air of several vine-growing regions of France. It is present in particle form in the environment; however, no study exploring its potential health impact on airways and the
M L Fernández-Cruz et al.
Food additives and contaminants, 23(6), 591-600 (2006-06-13)
The dissipation of residue levels of captan and trichlorfon in field-treated kaki crops was studied according to good laboratory practices to propose maximum residue limits (MRLs). Residue levels of captan and trichlorfon were analysed by GC/MS and LC-MS/MS, respectively. Residue
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