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Propargite

PESTANAL®, analytical standard, technical mixture

Synonym(s):

2-(4-tert-Butylphenoxy)cyclohexyl 2-propynyl sulfite

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About This Item

Empirical Formula (Hill Notation):
C19H26O4S
CAS Number:
2312-35-8
Molecular Weight:
350.47
Beilstein/REAXYS Number:
6934289
EC Number:
219-006-1
MDL number:
MFCD00072448
UNSPSC Code:
41116107
PubChem Substance ID:
329753981
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

Storage temp.

2-8°C

SMILES string

CC(C)(C)c1ccc(OC2CCCCC2OS(=O)OCC#C)cc1

InChI

1S/C19H26O4S/c1-5-14-21-24(20)23-18-9-7-6-8-17(18)22-16-12-10-15(11-13-16)19(2,3)4/h1,10-13,17-18H,6-9,14H2,2-4H3

InChI key

ZYHMJXZULPZUED-UHFFFAOYSA-N

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General description

Propargite, a non-systemic acaricide, is most commonly used on crops such as cotton, vines, nuts, tea etc for controlling phytophagous mite infestation.

Application

Propargite has been used as pesticide standard for determination of residual pesticides from:
  • Olive oil samples using GC–MS and HPLC–MS methods.
  • Tea leaf extract using GC-negative chemical ionization mass spectrometry (GC-NCI-MS) and UHPLC-tandem mass spectrometry (UHPLC-MS/MS).
  • Apple leaf extract using HPLC method.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Skin Irrit. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

160.5 °F - Pensky-Martens closed cup

flash_point_c

71.4 °C - Pensky-Martens closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCG9526
BCCC0412
BCBV0663
BCBS0305V
SZBD325XV

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Dissipation behavior of propargite--an acaricide residues in soil, apple (Malus pumila) and tea (Camellia sinensis).
Kumar V et.al.
Chemosphere, 58(6), 837-843 (2005)
Analysis of agricultural residues on tea using d-SPE sample preparation with GC-NCI-MS and UHPLC-MS/MS.
Zhang X
Journal of Agricultural and Food Chemistry, 58(22), 11553-11560 (2010)
L D Saunders et al.
Journal of occupational medicine. : official publication of the Industrial Medical Association, 29(5), 409-413 (1987-05-01)
An outbreak of dermatitis cases among 198 orange pickers employed by a Tulare County, California, packinghouse was investigated. Dermatitis was contracted by 114 (58%) of the 198 workers exposed when Omite-CR-treated fields were harvested. The dermatitis occurred predominantly in the
Vipin Kumar et al.
Chemosphere, 58(6), 837-843 (2004-12-29)
Propargite, recently introduced in India, is an effective acaricide on a large number of crops most of which are consumed by human beings directly or after processing. Therefore, it has become important to check the dissipation behavior of propargite in
Hanaa Zainal et al.
Journal of hazardous materials, 137(1), 165-171 (2006-05-23)
The goal of the study was to assess how protective disposable (Safeskin) and chemical protective (Sol-Vex) nitrile gloves were against Comite emulsifiable concentrate formulation containing propargite (PROP) as active pesticidal ingredient, because there were no explicit recommendations for the gloves
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