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Key Documents

21310

Sigma-Aldrich

(±)-Camphor

purum, synthetic, ≥95.0% (GC)

Synonym(s):

1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

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About This Item

Empirical Formula (Hill Notation):
C10H16O
CAS Number:
Molecular Weight:
152.23
Beilstein/REAXYS Number:
1907611
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

5.2 (vs air)

Quality Level

vapor pressure

4 mmHg ( 70 °C)

grade

purum

assay

≥95.0% (GC)

quality

synthetic

expl. lim.

3.5 %

impurities

≤0.5% water

bp

204 °C (lit.)

mp

175-177 °C (lit.)

solubility

ethanol: soluble 1 g/10 mL, clear, colorless
water: soluble

functional group

ketone

SMILES string

[H][C@](CC1=O)(CC2)C(C)(C)[C@]12C

InChI

1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

InChI key

DSSYKIVIOFKYAU-XCBNKYQSSA-N

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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 2 Inhalation

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 1

flash_point_f

147.9 °F - closed cup

flash_point_c

64.4 °C - closed cup

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Highly diastereoselective synthesis of new optically active aminoalcohols in one step from (+)-camphor and (-)-fenchone.
Genov M, et al.
Tetrahedron Asymmetry, 8(11), 1869-1876 (1997)
Planer nano-graphenes from camphor by CVD.
Somani PR, et al.
Chemical Physics Letters, 430(1), 56-59 (2006)
Christian Merten et al.
The journal of physical chemistry. A, 116(27), 7329-7336 (2012-06-06)
In the present work, the first observation of strong resonance Raman optical activity (RROA) involving more that one resonant electronic state is reported. The chiral transition metal complex bis-(trifluoroacetylcamphorato) copper(II), abbreviated Cu(tfc)(2), exhibits both resonance Raman (RR) and RROA spectra
Shigeki Yamamoto et al.
Journal of computational chemistry, 34(25), 2152-2158 (2013-07-05)
Induced resonance Raman optical activity (IRROA) proved to be a very sensitive method to detect molecular chirality. It is exhibited, for example, by complexes of lanthanides with chiral alcohols or ketones. So far, the phenomenon has not been understood at
Hong Zhang et al.
Analytica chimica acta, 742, 67-73 (2012-08-14)
A simple, sensitive and selective method for the simultaneous determination of five ultraviolet (UV) filters: benzophenone, octyl salicylate, homosalate, 3-(4-methylbenzylidene) camphor, 2-hydroxy-4-methoxybenzophenone in aqueous samples was developed. The analytes were extracted by plunger-in-needle solid-phase microextraction with graphene as sorbent, then

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