8.01812

Benzylamine

for synthesis

• Synonym(s): Benzylamine, Phenylmethylamine
• Empirical Formula (Hill Notation): C₇H₉N
• CAS Number: 100-46-9
• Molecular Weight: 107.15
• MDL number: MFCD00008106
• UNSPSC Code: 12352116
• EC Index Number: 202-854-1
• NACRES: NA.22

Properties

• vapor pressure: 1.2 hPa ( 20 °C)
• Quality Level: 200
• assay: ≥99.0% (GC)
• form: liquid
• autoignition temp.: 405 °C
• potency: 552 mg/kg LD₅₀, oral (Rat); 1350 mg/kg LD₅₀, skin (Rat)
• expl. lim.: 0.7-8.2 % (v/v)
• pH: 11.4 (20 °C, 100 g/L in H₂O)
• mp: -42.8 °C
• transition temp: flash point 72 °C
• density: 0.98 g/cm³ at 20 °C
• storage temp.: 2-30°C
• InChI: 1S/C7H9N/c8-6-7-4-2-1-3-5-7/h1-5H,6,8H2
• InChI key: WGQKYBSKWIADBV-UHFFFAOYSA-N

Description

Application

• Organic synthesis in water with covalent organic frameworks: Research on fully conjugated covalent organic framework nanosheets, facilitated by catalysts like benzylamine, demonstrates their effectiveness in visible-light-driven organic synthesis, promoting environmentally friendly chemical processes (Ma et al., 2024).
• Photocatalytic oxidation of amines with microporous polymers: Demonstrates the confined synthesis of conjugated microporous polymers, utilizing benzylamine as a substrate for selective photocatalytic oxidation of amines, a technique applicable in the purification of chemical substances and environmental cleanup (You et al., 2024).

Analysis Note

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.982 - 0.983
Water (K. F.): ≤ 0.25 %
Identity (IR): passes test

Safety Information

• pictograms: GHS05,GHS07
• signalword: Danger
• hcodes: H302 + H312 - H314
• pcodes: P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P362 + P364
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
• Storage Class: 8A - Combustible, corrosive hazardous materials
• wgk_germany: WGK 1
• flash_point_f: 149.0 °F - closed cup
• flash_point_c: 65 °C - closed cup