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Key Documents

E14705

Sigma-Aldrich

2-Ethyl-1-butene

95%

Synonym(s):

1,1-Diethylethene, 1,1-Diethylethylene, 3-Methylenepentane

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About This Item

Linear Formula:
CH3CH2C(C2H5)=CH2
CAS Number:
Molecular Weight:
84.16
Beilstein/REAXYS Number:
1697102
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

95%

form

liquid

autoignition temp.

599 °F

refractive index

n20/D 1.396 (lit.)

bp

64-65 °C (lit.)

mp

−131.5-−131 °C (lit.)

density

0.689 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCC(=C)CC

InChI

1S/C6H12/c1-4-6(3)5-2/h3-5H2,1-2H3

InChI key

RYKZRKKEYSRDNF-UHFFFAOYSA-N

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pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2 - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

14.0 °F - closed cup

flash_point_c

-10 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves


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Chemistry (Weinheim an der Bergstrasse, Germany), 27(7), 2513-2522 (2020-11-17)
The first intermolecular early main group metal-alkene complexes were isolated. This was enabled by using highly Lewis acidic Mg centers in the Lewis base-free cations (Me BDI)Mg+ and (tBu BDI)Mg+ with B(C6 F5 )4 - counterions (Me BDI=CH[C(CH3 )N(DIPP)]2
Kurtis M Carsch et al.
Science (New York, N.Y.), 365(6458), 1138-1143 (2019-09-14)
Terminal copper-nitrenoid complexes have inspired interest in their fundamental bonding structures as well as their putative intermediacy in catalytic nitrene-transfer reactions. Here, we report that aryl azides react with a copper(I) dinitrogen complex bearing a sterically encumbered dipyrrin ligand to

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