80613

(−)-trans-Pinocarveol

≥96.0% (sum of enantiomers, GC)

• Synonym(s): (1S,3R,5S)-2(10)-Pinen-3-ol, (1S,3R,5S)-6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptan-3-ol
• Empirical Formula (Hill Notation): C₁₀H₁₆O
• CAS Number: 547-61-5
• Molecular Weight: 152.23
• Beilstein/REAXYS Number: 5730571
• EC Number: 208-927-4
• MDL number: MFCD00210086
• UNSPSC Code: 12352002
• PubChem Substance ID: 57652835
• NACRES: NA.22

Properties

• assay: ≥96.0% (sum of enantiomers, GC)
• form: liquid
• optical activity: [α]20/D −72±3°, neat
• color: opaque white
• refractive index: n20/D 1.500
• density: 0.979 g/mL at 20 °C (lit.)
• SMILES string: CC1(C)[C@@H]2C[C@@H](O)C(=C)[C@H]1C2
• InChI: 1S/C10H16O/c1-6-8-4-7(5-9(6)11)10(8,2)3/h7-9,11H,1,4-5H2,2-3H3/t7-,8+,9+/m0/s1
• InChI key: LCYXQUJDODZYIJ-DJLDLDEBSA-N

Description

General description

(-)-trans-Pinocarveol is an allyl alcohol. It is formed during the allylic oxidation of β-pinene using hydrogen peroxide-selenium dioxide[1] or from the isomerization of α-pinene oxide over zirconium oxide.[2]

Other Notes

Volatile component of essential oils occurring in many plants. Starting material for highly pure (-)-nopinone[3]

Safety Information

• Storage Class: 12 - Non Combustible Liquids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves