772844

Cyclopropylmagnesium bromide solution

1.0 M in 2-methyltetrahydrofuran

• Synonym(s): Bromocyclopropylmagnesium
• Empirical Formula (Hill Notation): C₃H₅BrMg
• CAS Number: 23719-80-4
• Molecular Weight: 145.28
• MDL number: MFCD00672094
• UNSPSC Code: 12352103
• PubChem Substance ID: 329766610
• NACRES: NA.22

Properties

• form: solution
• reaction suitability: reaction type: Grignard Reaction
• greener alternative product characteristics: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• concentration: 1.0 M in 2-methyltetrahydrofuran
• density: 1.022 g/mL at 25 °C
• greener alternative category: Aligned,
• storage temp.: 2-8°C
• SMILES string: Br[Mg]C1CC1
• InChI: 1S/C3H5.BrH.Mg/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1
• InChI key: QUPLLJGAJVXXBW-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H261,H302,H314
• pcodes: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 2
• supp_hazards: EUH019
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• wgk_germany: WGK 3
• flash_point_f: -22.0 °F - closed cup
• flash_point_c: -30 °C - closed cup