68916
(R)-(−)-S-Methyl-S-phenylsulfoximine
≥99.0% (GC)
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About This Item
Empirical Formula (Hill Notation):
C7H9NOS
CAS Number:
Molecular Weight:
155.22
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
assay
≥99.0% (GC)
form
solid
optical activity
[α]/D −28.5±3, c = 1 in acetonitrile
SMILES string
C[S@@](=N)(=O)c1ccccc1
InChI
1S/C7H9NOS/c1-10(8,9)7-5-3-2-4-6-7/h2-6,8H,1H3/t10-/m1/s1
InChI key
YFYIDTVGWCYSEO-SNVBAGLBSA-N
Other Notes
A new class of C1-symmetric monosulfoximine ligands for enantioselective hetero Diels-Alder reactions: quinoline-based C1-symmetric sulfoximines lead to cycloadducts with up to 96% ee[1]
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Carsten Bolm et al.
Chemical communications (Cambridge, England), (22), 2826-2827 (2003-12-04)
Quinoline-based C1-symmetric sulfoximines have been used as chiral ligands in copper-catalyzed asymmetric hetero Diels-Alder reactions leading to cycloadducts with up to 96% ee.
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