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520721

Sigma-Aldrich

Iridium(III) chloride

99.8% trace metals basis

Synonym(s):

Iridium trichloride, Trichloroiridium

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1 G
$358.00

About This Item

Linear Formula:
IrCl3
CAS Number:
10025-83-9
Molecular Weight:
298.58
EC Number:
233-044-6
MDL number:
MFCD00011063
UNSPSC Code:
12352302
PubChem Substance ID:
24874162
NACRES:
NA.23
assay:
99.8% trace metals basis
form:
powder or crystals
solubility:
H2O: insoluble(lit.)
aliphatic hydrocarbons: insoluble(lit.)
aqueous acid: insoluble(lit.)

$358.00

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assay

99.8% trace metals basis

form

powder or crystals

impurities

≤2500.0 ppm Trace Metal Analysis

mp

763 °C (lit.)

solubility

H2O: insoluble(lit.)
aliphatic hydrocarbons: insoluble(lit.)
aqueous acid: insoluble(lit.)

SMILES string

Cl[Ir](Cl)Cl

InChI

1S/3ClH.Ir/h3*1H;/q;;;+3/p-3

InChI key

DANYXEHCMQHDNX-UHFFFAOYSA-K

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General description

Iridium(III) chloride is a crystalline inorganic solid with excellent electrical conductivity and good transmission in the infrared range. It is used in the field of catalysis and nanomaterial synthesis.[1] [2]

Application

Iridium(III) chloride can be used:
  • As a precursor to synthesize Iridium nanoparticles.[1]
  • As a starting material synthesize Iridium complexes that can be used to fabricate OLEDs.[3]
  • As a catalyst for the ring opening of epoxidesby aryl, heterocyclic, or aliphatic amines.[2]

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW8039
MKCT3508
MKCS8797
MKCT9162
MKCR9814

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Effective hydrogenation of Haloaromatic nitro compounds catalysed by iridium nanoparticles deposited on multiwall carbon nanotubes
Hua-Bin Li, et al.
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 46, 1499-1505 (2016)
Aminolysis of epoxides using iridium trichloride as an efficient catalyst
Jyoti Agarwal, et al.},
Synthesis, 2009, 2790-2796 (2009)
Ditopic bis-terdentate cyclometallating ligands and their highly luminescent dinuclear iridium (III) complexes
Pierre-Henri Lanoe, et al.
Chemical Communications (Cambridge, England), 50, 6831-6834 (2014)
Rajendra Prasad Paitandi et al.
European journal of medicinal chemistry, 84, 17-29 (2014-07-12)
Efficacy of the ferrocene appended piano-stool dipyrrinato complexes [(η(6)-C6H6)RuCl(fcdpm)] (1), [(η(6)-C10H14)RuCl(fcdpm)] (2), [(η(6)-C12H18)RuCl(fcdpm)] (3) [(η(5)-C5Me5)RhCl(fcdpm)] (4) and [(η(5)-C5Me5)IrCl(fcdpm)] (5) [fcdpm = 5-ferrocenyldipyrromethene] toward anticancer activity have been described. Binding of the complexes with calf thymus DNA (CT-DNA) and BSA (bovine

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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