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463310

Sigma-Aldrich

3,3′,4,4′-Biphenyltetracarboxylic dianhydride

97%

Synonym(s):

s-BPDA

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About This Item

Empirical Formula (Hill Notation):
C16H6O6
CAS Number:
Molecular Weight:
294.22
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

97%

mp

299-305 °C (lit.)

SMILES string

O=C1OC(=O)c2cc(ccc12)-c3ccc4C(=O)OC(=O)c4c3

InChI

1S/C16H6O6/c17-13-9-3-1-7(5-11(9)15(19)21-13)8-2-4-10-12(6-8)16(20)22-14(10)18/h1-6H

InChI key

WKDNYTOXBCRNPV-UHFFFAOYSA-N

General description

3,3′,4,4′-Biphenyltetracarboxylic dianhydride (s-BPDA) is a rigid symmetric polyamide with a diamine having a long distance between amine groups and reactive endgaps.

Application

s-BPDA can be used in the synthesis of high molecular weight aromatic polyamide fibers. It can also be used in the formation of hybrid nanocomposite films.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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High performance aromatic polyimide fibers, 3. A polyimide synthesized from 3, 3?, 4, 4?-biphenyltetracarboxylic dianhydride and 2, 2?-dimethyl-4, 4?-diaminobiphenyl
Eashoo M, et al.
Macromolecular Chemistry and Physics, 195(6), 2207-2225 (1994)
Microstructure and properties of 3, 3?, 4, 4?-biphenyltetracarboxylic dianhydride (BPDA)-p-phenylene diamine (PDA) polyimide/poly (vinylsilsesquioxane) hybrid nanocomposite films
Wahab MA, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 42(20), 5189-5199 (2004)
High thermal stable thermoplastic-thermosetting polyimide film by use of asymmetric dianhydride (a-BPDA)
Sasaki T, et al.
Polymer, 46(18), 6968-6975 (2005)
Mengjie Zhang et al.
Journal of colloid and interface science, 547, 136-144 (2019-04-06)
The aim of this study is to prepare a fibrous membrane scaffold that possesses a frogspawn structure for high-efficiency oil-water separation. Polyamic acid was first electrospun onto a rotating wheel-collector to obtain the fibrous membrane. Subsequently, post-processing by immersion in

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