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Sigma-Aldrich

Samarium(III) isopropoxide

99.9% trace metals basis

Synonym(s):

Samarium triisopropoxide, Tris(isopropoxy)samarium

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About This Item

Linear Formula:
Sm[OCH(CH3)2]3
CAS Number:
3504-40-3
Molecular Weight:
327.62
MDL number:
MFCD00058820
UNSPSC Code:
12352103
PubChem Substance ID:
24865693
NACRES:
NA.23

assay

99.9% trace metals basis

form

powder and chunks

reaction suitability

core: samarium
reagent type: catalyst

SMILES string

CC(C)O[Sm](OC(C)C)OC(C)C

InChI

1S/3C3H7O.Sm/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3

InChI key

HJCRVWSKQNDSPZ-UHFFFAOYSA-N

Application

Used with a dinucleating Schiff base ligand in a catalytic asymmetric nitro-Mannich reaction.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

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syn-Selective catalytic asymmetric nitro-Mannich reactions using a heterobimetallic Cu-Sm-Schiff base complex.
Shinya Handa et al.
Journal of the American Chemical Society, 129(16), 4900-4901 (2007-03-31)

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