366668

Diethyl (methylthiomethyl)phosphonate

96%

• Synonym(s): [(Methylthio)methyl]phosphonic acid diethyl ester
• Linear Formula: CH₃SCH₂P(O)(OC₂H₅)₂
• CAS Number: 28460-01-7
• Molecular Weight: 198.22
• MDL number: MFCD00015131
• UNSPSC Code: 12352108
• PubChem Substance ID: 24862686
• NACRES: NA.22

Properties

• assay: 96%
• form: liquid
• reaction suitability: reaction type: C-C Bond Formation
• refractive index: n20/D 1.465 (lit.)
• bp: 119-120 °C/10 mmHg (lit.)
• density: 1.13 g/mL at 25 °C (lit.)
• SMILES string: CCOP(=O)(CSC)OCC
• InChI: 1S/C6H15O3PS/c1-4-8-10(7,6-11-3)9-5-2/h4-6H2,1-3H3
• InChI key: RAABCCZMKIIGJW-UHFFFAOYSA-N

Description

Application

Reactant for:

• Synthesis of (+)-minfiensine via organocatalytic Diels-Alder/amine cyclization and 6-exo-dig radical cyclization
• Preparation of fused nitrogen, sulfur, and phosphorus containing-heterocycles and relevant difurylpyridazine phosphonates with antimicrobial activity
• Preparation of phosphorus and sulfur stereoisomers of Et menthyl [(methylsulfinyl)methyl]phosphonate

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 215.6 °F - closed cup
• flash_point_c: 102 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter