Skip to Content
MilliporeSigma
All Photos(1)

Documents

309559

Sigma-Aldrich

3-Bromo-2,2-dimethyl-1-propanol

96%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
BrCH2C(CH3)2CH2OH
CAS Number:
40894-00-6
Molecular Weight:
167.04
MDL number:
MFCD00004683
UNSPSC Code:
12352100
PubChem Substance ID:
24858738
NACRES:
NA.22

assay

96%

form

liquid

refractive index

n20/D 1.479 (lit.)

bp

184-187 °C (lit.)

density

1.358 g/mL at 25 °C (lit.)

SMILES string

CC(C)(CO)CBr

InChI

1S/C5H11BrO/c1-5(2,3-6)4-7/h7H,3-4H2,1-2H3

InChI key

KQOQXYPZBYTICM-UHFFFAOYSA-N

Related Categories

Application

3-Bromo-2,2-dimethyl-1-propanol was used in the synthesis of 3-bromo-2,2-dimethylpropanal by undergoing oxidation with pyridinium chlorochromate, mixed with silica, in dichloromethane.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Erika Leemans et al.
The Journal of organic chemistry, 73(4), 1422-1428 (2008-01-24)
1-Allyl- and 1-(3-phenylallyl)-substituted 4-(2-bromo-1,1-dimethylethyl)azetidin-2-ones were transformed into 3-substituted 7-alkoxy-5,5-dimethyl-1-azabicyclo[4.2.0]octane-8-ones through radical cyclization by means of n-tributyltin hydride and AIBN in toluene with excellent diastereocontrol (>or=99%). The radical cyclization of 4-(2-bromo-1,1-dimethylethyl)-1-(2-methylallyl)azetidin-2-ones afforded 8-alkoxy-3,6,6-trimethyl-1-azabicyclo[5.2.0]nonan-9-ones in good diastereomeric excess (75-78%). The reductive ring

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service