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About This Item
Linear Formula:
CH3CH2CH2C≡CCH3
CAS Number:
Molecular Weight:
82.14
Beilstein/REAXYS Number:
1731542
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
99%
refractive index
n20/D 1.414 (lit.)
bp
84-85 °C (lit.)
density
0.731 g/mL at 25 °C (lit.)
SMILES string
CCCC#CC
InChI
1S/C6H10/c1-3-5-6-4-2/h3,5H2,1-2H3
Inchi Key
MELUCTCJOARQQG-UHFFFAOYSA-N
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General description
Pd/SiO2 modified with ionic liquid catalyzed lead free stereoselective hydrogenation of 2-hexyne has been reported. Polymerization of 2-hexyne in toluene catalyzed by MoCl5.Ph4Sn and WCl6.Ph4Sn has been reported. Mechanism of hydrogenation of 2-hexyne in solution on selective and unselective bulk Pd has been investigated. Lanthanum-catalyzed dimerization of 2-hexyne has been reported.
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Polymerization of 2-hexyne and higher 2-alkynes catalyzed by MoCl5.Ph4Sn and WCl6.Ph4Sn .
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A simple Pd/SiO2 catalyst which was modified with the ionic liquid [BMPL][DCA] gave an excellent yield of 88% towards cis-2-hexene in the stereoselective hydrogenation of 2-hexyne. The catalyst outperforms, even at full conversion, the commonly used lead-poisoned, toxic Lindlar catalyst
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Silver ion or argentation chromatography utilizes stationary phases containing silver ions for the separation of unsaturated compounds. In this study, a mixed-ligand silver-based ionic liquid (IL) was evaluated for the first time as a gas chromatographic (GC) stationary phase for
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