283207

Magnesium bis(monoperoxyphthalate) hexahydrate

80%, technical grade

• Synonym(s): MMPP
• Linear Formula: (HO₂CC₆H₄CO₃)₂Mg·6H₂O
• Molecular Weight: 494.64
• EC Number: 279-013-0
• MDL number: MFCD00149614
• UNSPSC Code: 12352002
• PubChem Substance ID: 24857092
• NACRES: NA.22

Properties

• grade: technical grade
• assay: 80%
• reaction suitability: reagent type: oxidant
• greener alternative product characteristics: Designing Safer Chemicals; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 93 °C (dec.) (lit.)
• functional group: hydroperoxide
• greener alternative category: Aligned,
• SMILES string: O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO
• InChI: 1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2
• InChI key: WWOYCMCZTZTIGU-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product MMPP is an alternative to widely used oxidant MCPBA as it is cheap, stable in the solid state, safer in handling and easier to use and thus aligns with the principle "Designing Safer Chemicals". For more information see the below articles.
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones.
Magnesium Bis(monoperoxyphthalate) Hexahydrate (MMPP).
Highly efficient epoxidation of unsaturated steroids using magnesium bis(monoperoxyphthalate) hexahydrate.

Application

A safer, greener oxidizing reagent that is a suitable replacement for peroxycarboxylic acids and is capable of effecting many types of oxidation reactions.

Oxidation Reactions Using Magnesium Monoperphthalate: A Comparison with m-Chloroperoxybenzoic Acid

Reagent for:

• Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
• Oxidation rections under mild conditions
• Epoxidation of unsaturated steroids
• Synthesis of ring-B oxygenated steroids as anticancer agents

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H242,H314,H332
• pcodes: P210 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Acute Tox. 4 Inhalation - Eye Dam. 1 - Org. Perox. E - Skin Corr. 1C
• Storage Class: 5.2 - Organic peroxides and self-reacting hazardous materials
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves