270032
N,N′-Dimethylethylenediamine
85%
Synonym(s):
1,2-Bis(methylamino)ethane
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All Photos(2)
About This Item
Linear Formula:
CH3NHCH2CH2NHCH3
CAS Number:
Molecular Weight:
88.15
Beilstein/REAXYS Number:
878142
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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assay
85%
form
liquid
refractive index
n20/D 1.431 (lit.)
bp
119 °C (lit.)
density
0.819 g/mL at 20 °C (lit.)
functional group
amine
SMILES string
CNCCNC
InChI
1S/C4H12N2/c1-5-3-4-6-2/h5-6H,3-4H2,1-2H3
InChI key
KVKFRMCSXWQSNT-UHFFFAOYSA-N
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Application
N,N′-Dimethylethylenediamine was used to enhance CO2 adsorption. It was incorporated into H3[(Cu4Cl)3(BTTri)8 (CuBTTri; H3BTTri = 1,3,5-tri(1H-1,2,3-triazol-4-yl)benzene), a water-stable, triazolate-bridged framework, to form a metal–organic framework for CO2 separation.
Other Notes
remainder N-Methylethylenediamine
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
78.8 °F - closed cup
flash_point_c
26 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Enhanced carbon dioxide capture upon incorporation of N, N?-dimethylethylenediamine in the metal?organic framework CuBTTri.
McDonald TM, et al.
Chemical Science, 2(10), 2022-2028 (2011)
A Szent-Györgyi
Physiological chemistry and physics, 12(2), 99-110 (1980-01-01)
Most inanimate systems are build of closed-shell molecules in which electrons lack excitability and mobility. These electrons can be rendered reactive and mobile by taking out some of them, desaturating the system electronically. Single electrons can be taken out of
Mohamed R Shehata et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 91, 383-388 (2012-03-06)
Pd(dmen)Cl(2) complex was synthesized and characterized, where dmen=N,N-dimethylethylenediamine. Stoichiometry and stability constants of the complexes formed between [Pd(dmen)(H(2)O)(2)](2+) and various biologically relevant ligands such as amino acids, peptides and dicarboxylic acids are investigated at 25 °C and at constant 0.1M
Xiaohu Deng et al.
The Journal of organic chemistry, 74(15), 5742-5745 (2009-06-17)
CuI/L5 (N,N'-dimethylethylenediamine) proves to be an efficient catalyst system for the amination of arylhalides with guanidines. The same catalyst system is then successfully applied to the one-step synthesis of 1-H-2-amino-benzimidazoles through tandem aminations of 1,2-dihaloarenes in modest yields. This methodology
Chandi C Malakar et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(29), 8882-8885 (2012-06-26)
Water makes it possible: The Cu(2)O-catalyzed reaction between easily available o-bromobenzylbromides and benzamidines by using Cs(2)CO(3) as the base and N,N'-dimethylethylenediamine (DMEDA) as the additive in water as the solvent gives access to substituted quinazolines in a single step with
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