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241067

Sigma-Aldrich

2-Methoxyethylamine

99%

Synonym(s):

2-Aminoethyl methyl ether

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50 ML
$132.00

About This Item

Linear Formula:
CH3OCH2CH2NH2
CAS Number:
109-85-3
Molecular Weight:
75.11
Beilstein/REAXYS Number:
741854
EC Number:
203-712-1
MDL number:
MFCD00008180
UNSPSC Code:
12352100
PubChem Substance ID:
24854461
NACRES:
NA.22
form:
liquid
assay:
99%

$132.00

In StockDetails

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Quality Level

200

assay

99%

form

liquid

refractive index

n20/D 1.406 (lit.)

bp

95 °C (lit.)

density

0.864 g/mL at 25 °C (lit.)

functional group

amine
ether

SMILES string

COCCN

InChI

1S/C3H9NO/c1-5-3-2-4/h2-4H2,1H3

InChI key

ASUDFOJKTJLAIK-UHFFFAOYSA-N

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General description

Kinetics of reaction of 2-methoxyethylamine with guanosine 5′-phospho-2-methylimidazolide (2-MeImpG) was studied[1].

Application

2-Methoxyethylamine can be used as a reactant:
  • In the substitution reaction with phosphoimidazolide-activated derivatives of nucleosides[1].
  • To synthesize amides by reacting with carboxylic acids[2].
  • For the chemical modification of α-acrylated cross-linked polymer via aza-Michael addition[3].

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

53.6 °F

flash_point_c

12 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBK7617
STBK6591
STBK2929
STBJ4135
STBJ0155

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Mesoporous Structured Silica-An improved catalyst for direct amide synthesis and its application to continuous flow processing.
Comerford J, et al.
ARKIVOC (Gainesville, FL, United States) (2012)
A Kanavarioti et al.
The Journal of organic chemistry, 60(3), 632-637 (1995-02-10)
Aliphatic amines react with phosphoimidazolide-activated derivatives of guanosine and cytidine (ImpN) by replacing the imidazole group. The kinetics of reaction of guanosine 5'-phospho-2-methylimidazolide (2-MeImpG) with glycine ethyl ester, glycinamide, 2-methoxyethylamine, n-butylamine, morpholine, dimethylamine (Me2NH), ethylmethylamine (EtNHMe), diethylamine (Et2NH), pyrrolidine, and
Intrinsic green fluorescent cross-linked poly (ester amide) s by spontaneous zwitterionic copolymerization
Zia A, et al.
Biomacromolecules, 22, 4794-4804 (2021)
Nathan J Van Zee et al.
Nature, 558(7708), 100-103 (2018-06-01)
Water directs the self-assembly of both natural1,2 and synthetic3-9 molecules to form precise yet dynamic structures. Nevertheless, our molecular understanding of the role of water in such systems is incomplete, which represents a fundamental constraint in the development of supramolecular
Courtney H Fox et al.
Nature communications, 6, 7417-7417 (2015-07-16)
Dynamic covalent materials are stable materials that possess reversible behaviour triggered by stimuli such as light, redox conditions or temperature; whereas supramolecular crosslinks depend on the equilibrium constant and relative concentrations of crosslinks as a function of temperature. The combination

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