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234834

Sigma-Aldrich

Cyclopentadienyltitanium(IV) trichloride

97%

Synonym(s):

CpTiCl3

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1 G
$65.14
5 G
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About This Item

Empirical Formula (Hill Notation):
C5H5Cl3Ti
CAS Number:
1270-98-0
Molecular Weight:
219.32
MDL number:
MFCD00003724
UNSPSC Code:
12161600
PubChem Substance ID:
24854059
NACRES:
NA.22

$65.14

List Price$70.80Save 8%

In StockDetails

Request a Bulk Order

Quality Level

100

assay

97%

form

solid

reaction suitability

core: titanium
reagent type: catalyst

mp

210 °C (dec.) (lit.)

SMILES string

Cl[Ti](Cl)Cl.[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3ClH.Ti/c1-2-4-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3

InChI key

AENCLWKVWIIOQH-UHFFFAOYSA-K

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Application

Precusor for cyclopentadienyltitanium(IV) complexes, and used as catalysts for alkene polymerizations

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000238411
0000238418
0000223865
0000229634
MKBQ0353V

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Cyclopentadienylhafnium(IV) trichloride 97%

Sigma-Aldrich

484369

Cyclopentadienylhafnium(IV) trichloride

Ricci, G.; Italia, S. et al.
The Journal of Organic Chemistry, 451, 67-67 (1993)
David Hermann Lamparelli et al.
Polymers, 11(4) (2019-04-19)
The direct synthesis of syndiotactic polystyrene-block-polyethylene copolymer (sPS-b-PE) with a diblock structure has been achieved. The synthetic strategy consists of the sequential stereocontrolled polymerization of styrene and ethylene in the presence of a single catalytic system: cyclopentadienyltitanium(IV) trichloride activated by
McGrane, P. L.; Jensen, M. et al.
Journal of the American Chemical Society, 114, 5459-5459 (1992)
Erker, G.; Aulbach, M. et al.
Journal of the American Chemical Society, 115, 4590-4590 (1993)
Komal Sethi et al.
Journal of colloid and interface science, 456, 59-65 (2015-06-21)
In this paper, we report the synthesis, characterization of drug-doped organically modified titania nanoparticles, and their applications in sustained drug release. The drug-doped nanoparticles were synthesized in the hydrophobic core of oil-in-water microemulsion medium. Structural aspects obtained through TEM and

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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