233188
4′-(Trifluoromethyl)acetophenone
98%
Synonym(s):
4-Acetylbenzotrifluoride
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5 G
$124.00
25 G
$193.00
About This Item
Linear Formula:
CF3C6H4COCH3
CAS Number:
Molecular Weight:
188.15
Beilstein/REAXYS Number:
1870425
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
98%
form
solid
bp
79-80 °C/8 mmHg (lit.)
mp
30-33 °C (lit.)
functional group
fluoro
ketone
SMILES string
CC(=O)c1ccc(cc1)C(F)(F)F
InChI
1S/C9H7F3O/c1-6(13)7-2-4-8(5-3-7)9(10,11)12/h2-5H,1H3
InChI key
HHAISVSEJFEWBZ-UHFFFAOYSA-N
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General description
The enantioselective addition of dialkylzinc to 4′-(trifluoromethyl)acetophenone mediated by 1,2-bis(hydroxycamphorsulfonamido)cyclohexenes in the presence of titanium tetraisopropoxide has been investigated[1]. Phosphorescence emission spectra of 4′-(trifluoromethyl)acetophenone has been studied using pulsed source phosphorimetry[2].
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
183.2 °F - closed cup
flash_point_c
84 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Pulsed source, time resolved phosphorimetry determination of phosphorescence lifetimes.
Harbaugh KF, et al.
Analytical Chemistry, 45(2), 381-382 (1973)
Highly enantioselective addition of dialkylzinc reagents to ketones promoted by titanium tetraisopropoxide.
Yus M, et al.
Tetrahedron Asymmetry, 13(21), 2291-2293 (2002)
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