232181

Methyl 1-cyclohexene-1-carboxylate

≥97%

• Linear Formula: C₆H₉CO₂CH₃
• CAS Number: 18448-47-0
• Molecular Weight: 140.18
• Beilstein/REAXYS Number: 1071971
• EC Number: 242-331-5
• MDL number: MFCD00001544
• UNSPSC Code: 12352100
• PubChem Substance ID: 24853885
• NACRES: NA.22

Properties

• assay: ≥97%
• form: liquid
• bp: 190-192 °C; 58-60 °C/0.1 mmHg (lit.)
• density: 1.028 g/mL at 20 °C (lit.)
• SMILES string: COC(=O)C1=CCCCC1
• InChI: 1S/C8H12O2/c1-10-8(9)7-5-3-2-4-6-7/h5H,2-4,6H2,1H3
• InChI key: KXPWRCPEMHIZGU-UHFFFAOYSA-N

Description

Application

Methyl 1-cyclohexene-1-carboxylate was used in:

• diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols
• synthesis of methyl 7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate
• synthesis of ethyl 7-oxo-7b,8,9,10,11,11a-hexahydro-7H-benzo[b]phenaleno[2,1-d]furan-11a-carboxylate

Safety Information

• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 159.8 °F - closed cup
• flash_point_c: 71 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter