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230847

Sigma-Aldrich

5-Methyl-1,10-phenanthroline

≥99%

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About This Item

Empirical Formula (Hill Notation):
C13H10N2
CAS Number:
Molecular Weight:
194.23
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

≥99%

form

powder

mp

113-114 °C (lit.)

solubility

methanol: soluble 50 mg/mL, clear to slightly hazy, colorless to yellow

SMILES string

Cc1cc2cccnc2c3ncccc13

InChI

1S/C13H10N2/c1-9-8-10-4-2-6-14-12(10)13-11(9)5-3-7-15-13/h2-8H,1H3

InChI key

UJAQYOZROIFQHO-UHFFFAOYSA-N

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General description

5-Methyl-1,10-phenanthroline forms iron(II)-phenanthroline complexes and their gas-phase stabilities has been investigated in an electrospray ionization mass spectrometer.

Application

5-Methyl-1,10-phenanthroline was used in the determination of Cu(II) in duralmin alloy by capillary zone electrophoresis.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Sandor Keki et al.
Journal of the American Society for Mass Spectrometry, 17(7), 962-966 (2006-05-23)
The gas-phase stabilities of Fe(Phi)3(2+) complexes, where Phi represents the 1,10-phenanthroline, 5-chloro-1,10-phenanthroline, 5-methyl-1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline, and 4,7-diphenyl-1,10-phenanthroline ligands were investigated by collision-induced dissociation (CID) in the capillary-first skimmer region upon changing the voltage difference between the capillary and the skimmer. The
Zdeněk Trávníček et al.
Chemistry Central journal, 6(1), 160-160 (2012-12-22)
Inspired by the unprecedented historical success of cisplatin, one of the most important research directions in bioinorganic and medicinal chemistry is dedicated to the development of new anticancer compounds with the potential to surpass it in antitumor activity, while having
Capillary electrophoretic separation of several transition-metal ions as their complexes with 1, 10-phenanthroline derivatives and its application to the determination of copper in duralmin alloys.
Yokoyama T, et al.
Analytica Chimica Acta, 364(1), 75-81 (1998)
K Benjamin Garbutcheon-Singh et al.
Dalton transactions (Cambridge, England : 2003), 42(4), 918-926 (2012-09-29)
Twelve metallointercalators of the type [Pt(I(L))(A(L))](2+), where A(L) is either the R,R or S,S enantiomer of 1,2-diaminocyclopentane (DACP) and I(L) is either 1,10-phenathroline, 4-methyl-1,10-phenanthroline, 5-methyl-1,10-phenanthroline, 4,7-dimethyl-1,10-phenanthroline, 5,6-dimethyl-1,10-phenanthroline or 3,4,7,8-tetramethyl-1,10-phenanthroline, were synthesised, characterised and the cytotoxicity to the L1210 cell line
Tiffany K Rundstadler et al.
Molecules (Basel, Switzerland), 23(9) (2018-09-06)
Cancer stem cells (CSCs) are thought of as a clinically pertinent subpopulation of tumors, partly responsible for cancer relapse and metastasis. Research programs aimed at discovering anti-CSC agents have largely focused on biologics and purely organic molecules. Recently, we showed

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