Skip to Content
MilliporeSigma
All Photos(2)

Documents

193496

Sigma-Aldrich

2-Iodobenzyl chloride

98%

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
IC6H4CH2Cl
CAS Number:
59473-45-9
Molecular Weight:
252.48
EC Number:
261-779-2
MDL number:
MFCD00000898
UNSPSC Code:
12352100
PubChem Substance ID:
24851596
NACRES:
NA.22

assay

98%

form

powder

refractive index

n20/D 1.635 (lit.)

bp

147-149 °C/32 mmHg (lit.)

mp

29-31 °C (lit.)

SMILES string

ClCc1ccccc1I

InChI

1S/C7H6ClI/c8-5-6-3-1-2-4-7(6)9/h1-4H,5H2

InChI key

FTMNWZHKQGKKAU-UHFFFAOYSA-N

Related Categories

Application

2-Iodobenzyl chloride was used in the synthesis of:
  • succinimido[3,4-b]indane
  • 1,2,3,4,5,6-hexahydro-1,5-methano-3-benzazocine-2,4-dione
  • 1-(2-iodobenzyi)-1,1-diethylamine
  • 1-(2-iodobenzyl)pyrrolidine
  • 1-(2-iodobenzyl)piperidine
  • 1-(2-iodobenzyl)hexahydroazepine
  • 4-(2-iodobenzyl)morpholine
  • 4-(2-iodobenzyl)thiomorpholine
  • 1-benzoyl-4-(2-iodobenzyl)piperazine
  • 1-(2-iodobenzyl)indole-2-carbaldehyde

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H314,H335

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

An Approach to α-substituted Amines.
Williams L, et al.
Tetrahedron, 50(48), 13697-13708 (1994)
Sushama A. Dandekar et al.
The Journal of organic chemistry, 64(5), 1543-1553 (2001-10-25)
The tricyclic title compounds, 4 and 5, were synthesized by initial alkylation of the lithium monoenolates of N,N,N',N'-tetramethylbutanediamide (6) and N,N,N',N'-tetramethylpentanediamide (19) with 2-iodobenzyl chloride in liquid NH(3) at -60 degrees C to afford 2-(2-iodobenzyl)-N,N,N',N'-tetramethylbutanediamide (9) and 2-(2-iodobenzyl)-N,N,N',N'-tetramethylpentanediamide (20) in
1-Azatriene cyclisation as a route to annelated pyrido [4, 3-b] indoles.
Gilchrist TL ,et al.
Tetrahedron, 53(12), 4447-4456 (1997)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service