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192376

Sigma-Aldrich

4-Bromo-2,6-dimethylaniline

98%

Synonym(s):

4-Bromo-2,6-xylidine

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About This Item

Linear Formula:
BrC6H2(CH3)2NH2
CAS Number:
24596-19-8
Molecular Weight:
200.08
Beilstein/REAXYS Number:
1936300
EC Number:
246-337-9
MDL number:
MFCD00007826
UNSPSC Code:
12352100
PubChem Substance ID:
24851542
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

200

assay

98%

form

solid

mp

48-51 °C (lit.)

functional group

bromo

SMILES string

Cc1cc(Br)cc(C)c1N

InChI

1S/C8H10BrN/c1-5-3-7(9)4-6(2)8(5)10/h3-4H,10H2,1-2H3

InChI key

QGLAYJCJLHNIGJ-UHFFFAOYSA-N

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Application

4-Bromo-2,6-dimethylaniline has been used in the preparation of:
  • 4-bromo-N-(1-(6-(1-isopropyl-1H-benzo[d]imidazol-2-yl)pyridin-2-yl)ethylidene)-2,6-dimethylbenzenamine[1]
  • N-(4-Bromo-2,6-dimethylphenyl)-5-trimethylammoniumsalicylaldimine chloride[2]
  • ethynyl-functionalized persistent perylene diimide-multichromophore[3]

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF3933V
BCCH0528
BCCJ4260
MKCQ6571
WXBD5425V

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2-(1-Isopropyl-2-benzimidazolyl)-6-(1-aryliminoethyl) pyridyl transition metal (Fe, Co, and Ni) dichlorides: syntheses, characterizations and their catalytic behaviors toward ethylene reactivity.
Chen Y, et al.
Journal of Organometallic Chemistry, 693(10), 1829-1840 (2008)
Energy and electron transfer in ethynylene bridged perylene diimide multichromophores.
Flors C, et al.
The Journal of Physical Chemistry C, 111(12), 395-404 (2007)
Joseph B Binder et al.
Advanced synthesis & catalysis, 349(3), 395-404 (2007-02-02)
Tuning the electronic and steric environment of olefin metathesis catalysts with specialized ligands can adapt them to broader applications, including metathesis in aqueous solvents. Bidentate salicylaldimine ligands are known to stabilize ruthenium alkylidene complexes, as well as allow ring-closing metathesis

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