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About This Item
Linear Formula:
C3H5CH2Cl
CAS Number:
Molecular Weight:
90.55
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.435 (lit.)
bp
87-89 °C (lit.)
density
0.98 g/mL at 25 °C (lit.)
functional group
chloro
SMILES string
ClCC1CC1
InChI
1S/C4H7Cl/c5-3-4-1-2-4/h4H,1-3H2
InChI key
ZVTQWXCKQTUVPY-UHFFFAOYSA-N
General description
(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
Application
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.
accessory
Product No.
Description
Pricing
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
28.4 °F - closed cup
flash_point_c
-2 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Unexpected reactions of an isolable dialkylsilylene with Haloalkanes.
Ishida S, et al.
Chemistry Letters (Jpn), 11, 1102-1103 (2001)
Easy selective generation of (lithiomethyl) cyclopropane or homoallyllithium by a chlorine-lithium exchange.
Pastor IM, et al.
Tetrahedron Letters, 49(48), 6870-6872 (2008)
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