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180033

Sigma-Aldrich

4-Methoxy-N-methylaniline

98%

Synonym(s):

N-Methyl-p-anisidine

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About This Item

Linear Formula:
CH3OC6H4NHCH3
CAS Number:
5961-59-1
Molecular Weight:
137.18
Beilstein/REAXYS Number:
774640
EC Number:
227-735-1
MDL number:
MFCD00008399
UNSPSC Code:
12352100
PubChem Substance ID:
24850845
NACRES:
NA.22

assay

98%

form

solid

bp

135-136 °C/19 mmHg (lit.)

mp

33-36 °C (lit.)

SMILES string

CNc1ccc(OC)cc1

InChI

1S/C8H11NO/c1-9-7-3-5-8(10-2)6-4-7/h3-6,9H,1-2H3

InChI key

JFXDIXYFXDOZIT-UHFFFAOYSA-N

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General description

The allylation of N-methyl-p-anisidine by quaternary allylammonium cation was studied.

Application

4-Methoxy-N-methylaniline (N-Methyl-p-anisidine) was used to study the additive effects of amines.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)

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Andrea Cappelli et al.
Bioorganic & medicinal chemistry, 16(6), 3428-3437 (2008-02-26)
The exploration of the structure-affinity relationships concerning a new class of peripheral benzodiazepine receptor (PBR) ligands related to alpidem has been pursued in order to evaluate the consistency of the structure-affinity relationships among different classes (and subclasses) of PBR ligands.
Takuto Nagano et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(37), 11578-11592 (2012-08-24)
The additive effects of amines were realized in the asymmetric hydrogenation of 2-phenylquinoxaline, and its derivatives, catalyzed by chiral cationic dinuclear triply halide-bridged iridium complexes [{Ir(H)[diphosphine]}(2)(μ-X)(3)]X (diphosphine = (S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl [(S)-BINAP], (S)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole [(S)-SEGPHOS], (S)-5,5'-bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole [(S)-DIFLUORPHOS]; X = Cl, Br, I) to

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