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151386

Sigma-Aldrich

Fumaryl chloride

95%

Synonym(s):

(2E)-2-Butenedioyl dichloride, Fumaric acid chloride, Fumaric acid dichloride, Fumaric dichloride, Fumaroyl dichloride, Fumaryl dichloride

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About This Item

Linear Formula:
ClCOCH=CHCOCl
CAS Number:
627-63-4
Molecular Weight:
152.96
Beilstein/REAXYS Number:
1721342
EC Number:
211-005-4
MDL number:
MFCD00000733
UNSPSC Code:
12352100
PubChem Substance ID:
24849125
NACRES:
NA.22

Quality Level

200

assay

95%

form

liquid

refractive index

n20/D 1.499 (lit.)

bp

161-164 °C (lit.)

density

1.415 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClC(=O)\C=C\C(Cl)=O

InChI

1S/C4H2Cl2O2/c5-3(7)1-2-4(6)8/h1-2H/b2-1+

InChI key

ZLYYJUJDFKGVKB-OWOJBTEDSA-N

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General description

The photodissociation dynamics of fumaryl chloride was studied.

Application

Fumaryl chloride was used in the preparation of high molecular weight poly(propylene fumarate).

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Seyed Amin Mirmohammadi et al.
Materials science & engineering. C, Materials for biological applications, 68, 530-539 (2016-08-16)
Hydroxyl functionalized nano-sized POSS or ethyleneglycol as diol monomers was incorporated to hydroxyl-terminated polybutadiene (HTPBD) chain in the presence of fumaryl chloride as extender. Blue light photocrosslinking system based on camphorquinone (photoinitiator) and dimethylaminoethyl methacrylate (accelerator) was applied to cure
Monali Kawade et al.
The journal of physical chemistry. A, 115(9), 1538-1546 (2011-02-17)
The photodissociation dynamics of fumaryl chloride (ClCO-CH═CH-COCl) has been studied in a supersonic molecular beam around 235 nm using resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) technique by detecting the nascent state of the primary chlorine atom. A single laser
Sepideh Koosehgol et al.
Materials science & engineering. C, Materials for biological applications, 79, 66-75 (2017-06-21)
In the present study, polyethylene glycol fumarate (PEGF) was synthesized as a component of blend solutions via polycondensation polymerization and characterized by different tests in order to determine its functional groups and its physical properties included melting and crystallization temperature
Irrum Mushtaq et al.
Materials science & engineering. C, Materials for biological applications, 108, 110456-110456 (2020-01-12)
Under different pathological conditions, high levels of reactive oxygen species (ROS) cause substantial damage to multiple organs. To counter these ROS levels in multiple organs, we have engineered highly potent novel terpolymers. We found that combination of FDA-approved polyethylene glycol
S J Peter et al.
Journal of biomaterials science. Polymer edition, 10(3), 363-373 (1999-04-03)
To synthesize high molecular weight poly(propylene fumarate) (PPF), fumaryl chloride and propylene glycol were reacted in the presence of potassium carbonate, which serves as a proton scavenger. Transesterification of the resulting low molecular weight oligomer led to a polymer with
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