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Key Documents

138029

Sigma-Aldrich

Furil

98%

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About This Item

Empirical Formula (Hill Notation):
C10H6O4
CAS Number:
Molecular Weight:
190.15
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

98%

form

solid

mp

163-165 °C (lit.)

SMILES string

O=C(C(=O)c1ccco1)c2ccco2

InChI

1S/C10H6O4/c11-9(7-3-1-5-13-7)10(12)8-4-2-6-14-8/h1-6H

InChI key

SXPUVBFQXJHYNS-UHFFFAOYSA-N

Gene Information

General description

Furil undergoes catalytic asymmetric transfer hydrogenation to yield hydrofuroin[1].

Application

Furil was used in preparation of dioxomolybdenum(VI) complexes in situ[2].

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Anzhelika Kabro et al.
Organic letters, 14(15), 4014-4017 (2012-07-27)
Catalytic asymmetric transfer hydrogenation of rac-furoin and furil produces hydrofuroin with up to 99% ee and 9:1 dr. This reaction provides an exceptionally easy access to optically active hydrofuroins in two straightforward steps from biomass-derived furfural (global production 200,000-300,000 t
Syntheses and spectroscopic studies on macrocyclic complexes of dioxomolybdenum (VI) with furil as precursor.
Rao DP, et al.
E-Journal of Chemistry, 9(2), 497-503 (2012)

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